Water solubility

Solubility of substances in water
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water solubility
In a narrow sense, it refers to the solubility of matter in water, and in a broad sense, it refers to the solubility of matter in water Polar solvent Dissolution properties in.
Chinese name
Water solubility
Foreign name
water solubility
Narrow sense
material Solubility in water
Generalized
Solubility of substances in polar solvents

brief introduction

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Water soluble lace fabric
have water Soluble substances usually contain Polar group Such as- OH 、-SO3H、- NH2 , - NHR, - COOH, etc. or not too long Carbon chain Water is the cheapest solvent, with wide sources and no pollution. Water soluble polymer It is soluble in water because of the polarity between water molecule and polymer Lateral base A hydrogen bond is formed between them. The dissolution of water-soluble polymers has an important condition, that is Solubility parameter Must be close, but this is only soluble necessary condition Instead of sufficient condition And the polymer Crystalline structure Impact.
For example, water soluble resin is called Water soluble resin The coating with water-soluble resin as the main component is called Water soluble paint , water soluble phosphate fertilizer Water soluble phosphate fertilizer
Water soluble color lead Water soluble glue Water soluble condom Water soluble Pearl powder Water soluble resin

Water soluble polymer

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PAM )Water soluble high molecular polymer, insoluble in most Organic solvent , with good Flocculability , which can reduce the friction resistance between liquids, and can be divided into non-ionic anion cation And hermaphrodite.

Anionic polyacrylamide

Anionic polyacrylamide (APAM) Product description: anionic polyacrylamide (APAM) is white powder particle in appearance. Its molecular weight ranges from 6 million to 25 million. It is well soluble in water and insoluble in organic solvents in any proportion. effective PH value Range 7 to 14, neutral Alkaline medium Medium high Polymer electrolyte Properties of, and salts electrolyte Sensitive, and high price metal ion It can be crosslinked into insoluble Gel
Industrial wastewater treatment : For suspended particles , higher concentration, positively charged particles, neutral or alkaline PH value of water, steel plant wastewater, Electroplating factory Wastewater, metallurgical wastewater, Coal washing wastewater And other sewage treatment, with the best effect. Drinking water treatment: many in China waterworks The water source of is from rivers. The content of sediment and minerals is high, and it is relatively turbid. Although it has been precipitated and filtered, it still cannot meet the requirements, so it needs to be added flocculant , dosage is inorganic flocculants 1/50, but the effect is several times that of inorganic flocculant. For rivers with serious organic pollution, inorganic flocculant and Cationic polyacrylamide The effect is better when used together. Recovery of lost starch distillers' grains from starch factories and alcohol factories: many starch factories' wastewater contains a lot of starch, which is now added Anionic polyacrylamide , make starch particles flocculent settling , and then precipitate through Filter press The pressed filter becomes cake and can be used as feed. The alcohol in the alcohol factory can also be dehydrated by anionic polyacrylamide and recovered by pressing filter. For rivers cement paste Settlement. For paper making Dry strength agent
be used for Papermaking additive Promoter. Add trace PAM-LB-3 into the pump inlet pulp storage tank before papermaking anion Polyacrylamide can make the filler in water and Microfiber Increase online retention by 20-30%. 20-30kg of pulp can be saved per ton.
For example: a large amount of waste water is generated during coal washing Emission pollution The environment must be recycled after sedimentation. The recovery of coal slime in water is also valuable, but it takes time and effort to rely on natural sedimentation, and the water is also unclear.
In addition, anionic polyacrylamide Perfuming The application of the industry is also becoming more and more popular. The characteristics of anionic polyacrylamide products are: good solubility, high viscosity, strong toughness, inflammability without smoke (less), combustion without odor, non-toxic, etc; Product performance Stable, avoiding other plants Colloidal powder Different from ordinary starch in origin and time, the bonding quality is uneven, and the formula needs to be adjusted repeatedly in the production of fragrance industry to avoid causing product quality Unstable phenomenon; Fragrance products have smooth and smooth appearance, good molding and are not easy to break; In particular, its cold water gelatinization property eliminates the need for boiling, and the materials can be directly mixed evenly. It can be produced by mixing with water. Moreover, the materials after mixing with water will not be hard and dry for a long time, which effectively saves energy and facilitates the
Production operation.
Use effect : The incense paste (incense product) made with this product has a flat appearance, no fracture, no mold, strong bending resistance, good color, no fading after drying, and sufficient ignition time, flammability Good. The iron plate does not "break the end", which is conducive to improving the volatilization rate of effective ingredients of mosquito repellent incense and reducing the loss of finished products in the drying process. At the same time, it can greatly reduce workers' labour intensity , improve work efficiency In addition, the product does not pollute the environment and can meet Green and environmental protection Requirements for products.
economic performance : Using this product can reduce the cost of raw materials by 5-12% and save energy by 20-30%.

Cationic polyacrylamide

Cationic polyacrylamide (CPAM) Product characteristics : The appearance of cationic polyacrylamide (CPAM) is white powder particles, Ionicity It has good solubility from 20% to 55% water, can be dissolved in water in any proportion and is insoluble in organic solvents. It has the characteristics of high polymer electrolyte and is suitable for those with negative charge and rich in organic matter waste water treatment Suitable for dyeing, papermaking, food, construction metallurgy , mineral processing, coal powder, oil field, aquatic processing and fermentation industries, especially suitable for wastewater treatment with high organic colloid content urban sewage Municipal sludge , paper sludge and others Industrial sludge Dehydration treatment.
purpose
(1) For Sludge dewatering The corresponding model of this product can be selected according to the nature of the sludge, which can effectively dewater the sludge before it enters the filter press. During dewatering, large flocs will be generated, which will not stick to the filter cloth, and will not disperse and flow during the filter press Mud cake Thick, high dewatering efficiency, mud cake Water content Below 80%.
(2) For domestic sewage and Organic wastewater The product shows positive electricity in the mixed or alkaline medium, so it can flocculate and precipitate the sewage with negative charge of suspended particles in the sewage and clarify effectively. Such as grain production Alcohol wastewater Papermaking wastewater Urban sewage treatment plant Waste water, Beer Wastewater, monosodium glutamate factory wastewater, refine sugar Wastewater, high organic content wastewater, feed wastewater, Textile printing and dyeing wastewater Wait, use Cationic polyacrylamide It is better than using anions Nonionic polyacrylamide or inorganic salt The effect of this kind of wastewater is several times or dozens of times higher, because this kind of wastewater generally carries negative charges.
(3) Flocculant used for the treatment of tap water with river water as the source has low dosage, good effect and low cost, especially when combined with inorganic flocculant, it will become a treatment agent Yangtze River Yellow River And other river basin waterworks.
(4) For paper making Enhancer And other additives. Improve the retention rate of fillers and pigments, and the strength of paper.
(5) Used as oilfield economic aids, such as clay anti swelling agent and oilfield acidizing agent Thickener
(6) For textile Sizing agent Stable size performance, less size dropping, low fabric end breakage rate and smooth cloth surface.

Nonionic polyacrylamide

Product characteristics:
Nonionic polyacrylamide Series of products It is linear with high molecular weight and low ionic degree high polymer Because of its special group, it has the functions of flocculation, dispersion, thickening, bonding, film forming, gel and colloid stabilization. Sewage treatment agent : When Levitation When the sewage is acidic, it is appropriate to use non-ionic polyacrylamide as flocculant. Then PAM starts Adsorption bridging Function Particle production Flocculation and sedimentation can purify sewage. It can also be used for the purification of tap water, especially in combination with inorganic flocculants, which has the best effect in water treatment.
Application:
1. It is widely used in industrial wastewater treatment, and has the best treatment effect for suspended particles, coarse, high concentration, cationic ions, neutral or alkaline PH value of water, steel plant wastewater, metallurgical wastewater, coal washing wastewater, etc.
2. For petroleum industry , oil production Drilling mud waste mud treatment Prevent water channeling, reduce friction and improve recovery ratio Tertiary oil recovery It is widely used.
3. It is used as textile sizing agent, with stable sizing performance, less size dropping, low fabric end breakage rate and smooth cloth surface.
4. For paper industry First, improve the retention rate of fillers and pigments; The second is to improve the strength of the paper (including Dry strength and Wet strength )。 In addition, it can also improve the tear resistance and porosity of the paper to improve the visual and printing performance. It is also used for food and tea packing paper Medium.

About solvents

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Solvents are generally divided into two categories: Polar solvent Non-polar solvent Solvent type and substance Solubility The relationship between the two can be summarized as: "dissolve the similarity". It means that polar solvent can dissolve Ionic compound And can dissociation Of Covalent compound Non polar solvents can only dissolve non-polar covalent compounds. For example, table salt is an ionic compound that can be dissolved in water, but cannot ethanol Moderately dissolved.
stay Organic chemistry The solvents commonly used in acetone , ethanol, water and benzene.
Water and non-polar solvents cannot mutually dissolvable In particular, water and ethanol are mutually soluble in any ratio; If you have to do this, they will not form a uniform mixture and will eventually separate into two layers, which is called Suspension , or add corresponding additives (commonly used in pesticides) to the oil, Water ingress Post formation Oil in water or Water in oil A homogeneous emulsion of.
Solubility [1] Relevant knowledge and application of
① It means that the substance is in the solvent Solubility Size of.
② Solubility is physical property Dissolution is a physical change. (There are also chemical changes)
③ Solubility is determined by solubility Determined. (solid)
solubility
Insoluble
Slightly soluble
soluble
Soluble
20℃
<0.01g
0.01~1g
1g~10g
>10g
④ The following applications can be achieved by using solubility:
a、 Judge gas collection method
Soluble( Soluble )Gas in water cannot be extracted by drainage method
E.g. C O2 and H2 The solubility of O2 is poor, so the drainage method can be used.
b、 Judge mixture separation method
When the solubility of two substances in water is obviously different, they can be used Filtration method Separation.
For example: KNO3 (soluble) and CaCO3 ( Insoluble )It can be separated by filtration;
C and MnO2 Both are insoluble NaCl KNO3 is soluble and cannot be separated by filtration.
Solubility algorithm: solute mass/solvent mass (usually water)
Unit: g/100g water
Partially acid, alkali and salt Solubility table (20℃)
OH-NO3-Cl-SO42-CO32-
H+(water) soluble, volatile( nitric acid )Dissolve and volatilize
hydrochloric acid )Dissolve (sulfuric acid) Dissolve and volatilize( carbonic acid
NH4+ Dissolve and volatilize( ammonia Ammonium hydroxide )Soluble
K+dissolving( Caustic potash )Soluble
Na+solution( sodium hydroxide )Soluble
Ba2+solubility
Ca2+micro( Hydrated lime )Slightly insoluble
Mg2+insoluble
Al3+insoluble-
Mn2+insoluble insoluble
Zn 2+insoluble insoluble
Fe2+insoluble insoluble
Fe3+insoluble-
Cu2+insoluble-
Ag+- slightly soluble
Note: "Soluble" means that the substance is soluble in water, "non" means that it is insoluble in water, "micro" means that it is slightly soluble in water, and "volatile" means that it is slightly soluble in water volatility , "-" means that the substance does not exist or decomposes when encountering water.
Soluble formula (easy for students to learn and remember)

Soluble Formula I

Potassium and sodium ammonium salt Quick water dissolving, ①
sulfate Remove barium, lead and calcium. ②
Nitrate The solution is transparent. ③
Not everything in the pithy formula sinks. ④
Note:
① Potassium, sodium and ammonium salts are soluble in water;
③ Nitrates are soluble in water;
④ Not involved in the formula salt Are insoluble in water;

Soluble Formula II

Potassium, sodium, ammonium salt, nitrate;
Silver and mercury removal by chloride;
Barium and lead removal by sulfate;
Carbonic acid phosphate , only soluble potassium, sodium and ammonium.

Soluble Formula 3

Potassium, sodium, ammonium and nitrate are soluble, and silver and mercury are insoluble in hydrochloride;
Sulfate insoluble barium and lead, carbophosphate are mostly insoluble.
Most acid soluble alkali less soluble, only potassium sodium ammonium barium soluble

Soluble Formula IV

Potassium, sodium, nitric acid soluble( sylvite , sodium salt and nitrate are soluble in water.)
Removal of silver (mercurous) from hydrochloric acid Mercurous chloride It is soluble outside.)
In addition, there should be no barium or lead in sulfate (barium sulfate and lead sulfate are insoluble in sulfate)
Other types of salt( carbonate Sulfite , phosphate silicate and sulfide
Only potassium, sodium and ammonium are soluble (only the corresponding potassium salt, sodium salt and ammonium salt are soluble)
Finally, alkalis, potassium, sodium, ammonium and barium. Potassium hydroxide , sodium hydroxide Barium hydroxide And ammonia soluble)
There are several other slightly soluble substances, which can be remembered separately.

Soluble Formula 5

Potassium sodium ammonium nitrate
Complete dissolution is not difficult
Mercurous chloride silver chloride
Barium sulfate and lead sulfate
Precipitation generating cardiac room
Hydrogen sulfate and alkali
carbonic acid phosphoric acid Nitrate
Only potassium, sodium and ammonium are soluble
Soluble Formula 6
Potassium sodium ammonium nitrate solution
Strongly soluble and weakly insoluble
Soluble Formula 7:
Potassium sodium ammonium salt solution
No trace of nitrate entering water
Removal of silver and mercury by chloride
Barium sulfate lead insoluble in water
Carbonate soluble potassium sodium ammonium
Alkali soluble potassium calcium sodium barium ammonium
Special case: 1 perchloric acid Potassium, rubidium, Cesium salt The solubility is very small
2. Silver perchlorate Very high solubility, 5570g/L
3. Silver fluoride Soluble in water, and the solubility is relatively high. 1800g/L

Soluble Formula 6

Potassium, sodium, ammonium nitrate, all dissolved in water
Carbon and phosphate are mostly insoluble, only potassium, sodium and ammonium are soluble
Silver chloride and barium sulfate, insoluble nitric acid
barium carbonate , calcium oxyhydroxide (magnesium hydroxide), white precipitate soluble in acid
Copper hydroxide Blue, soluble potassium sodium barium calcium base