Unsaturated hydrocarbon

[bù bǎo hé tīng]
Hydrocarbon compounds with carbon carbon double bond or triple bond in the molecule
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Unsaturated hydrocarbon, which is composed of Carbon carbon double bond or Triple bond Of Hydrocarbons chemical compound The unsaturated hydrocarbon with double bond is called "olefin", which is hydrogen atom "Sparse" means less; yes Triple bond It means that the hydrogen atom is deficient. In addition Aromatic hydrocarbon , such as "benzene". The double bond and triple bond of unsaturated hydrocarbon are not very firm, which are relatively easy to break, and are prone to electrophilic substitution reaction and electrophilic reaction Addition reaction [1] With carbon carbon double bond olefin , which includes Monoolefin Diene and Polyolefin contain Carbon carbon triple bond Yes Alkyne Unsaturated hydrocarbon can also be divided into unsaturated chain hydrocarbon and unsaturated hydrocarbon according to different carbon frame structures cyclic hydrocarbon This chapter Monoolefins, alkynes and dienes are mainly discussed. [1]
Chinese name
Unsaturated hydrocarbon
Foreign name
unsaturated hydrocarbon
Definition
Hydrocarbon compounds with carbon carbon double bond or triple bond in the molecule

structure

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If only Single bond , is called Saturated hydrocarbon , like the following formula, it belongs to saturated chain hydrocarbon in saturated hydrocarbon, and saturated chain hydrocarbon is called alkane Alkane means "complete". There are only single bonds and chains in the molecule.
H H
Unsaturated hydrocarbon
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H—C—C—H
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H H
If the bonds are not filled with hydrogen atoms, the remaining bonds will be carbon atom Form double bond or Triple bond Is unsaturated hydrocarbon, as follows:
H H
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C=C H—C≡C—H
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H H
Those with double bonds are called "alkenes", which means that hydrogen atoms are "rare"; The triple bond is "acetylene", which means that the hydrogen atom is "deficient".
In addition Aromatic hydrocarbon , for example“ benzene ”。 Molecular formula "C6H6". by Organic chemical industry One of the basic raw materials of. Colorless, flammable and special smelling liquid. Melting point 5.5 ℃, boiling point 80.1 ℃, relative density 0.8765(20/4℃)。 Underwater solubility Very small, can match ethanol Ether carbon disulfide etc. Organic solvent Miscibility Can form with water Azeotropic mixture , boiling point is 69.25 ℃, containing 91.2% benzene. Therefore, benzene distillation is often added in the reaction with water formation to Water hose Out. When benzene burns, it produces thick smoke.
Benzene can rise Substitution reaction Addition reaction and oxidation reaction Benzene nitric acid Nitrification of mixture with sulfuric acid nitrobenzene Nitrobenzene is reduced to produce aniline, an important dye intermediate.

purpose

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Benzene mainly comes from Architectural decoration Chemical raw materials, such as coatings Wood lacquer Adhesives and various organic solvents.

matters needing attention

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During the film forming and curing process of the coating formaldehyde , benzene and other volatile components will be released from the paint, causing pollution. International Health Organization Benzene has been rated as strong Carcinogen , long-term inhalation will damage human body circulatory system And hematopoietic function, leading to leukemia In addition, women are particularly sensitive to benzene inhalation, Pregnancy Long term inhalation of benzene in women can cause Fetal development Deformities and miscarriages. Experts call it "aromatic killer".

stability

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Because the double bond is composed of a σ bond And a pi bond And Triple bond It is composed of one σ bond and two π bonds. The electron group of π bond is exposed to the periphery of the bond, which is easy to attract Electrophilic body , carry out electrophilic substitution reaction and electrophilic Addition reaction Therefore, in general, the double bond and triple bond of unsaturated hydrocarbon are not very firm and are relatively easy to break.

name

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Unsaturated hydrocarbon carbon atom How many names, such as two carbon atoms olefin call ethylene Alkyne call acetylene , three are called propylene or Propargyl Etc. Take a closer look IUPAC nomenclature And Chinese IUPAC nomenclature.