carbon atom

The most basic elements of organisms
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Carbon Chemical symbol :C element Atomic weight :12.011 Proton number :6 Atomic number : 6 cycles: 2 family :IVA
There are three types of naturally generated carbon isotope form: twelve C and thirteen C is stable isotope , and fourteen C has radioactivity , which half life About 5730 years. Carbon is one of the few elements found since ancient times Carbon based organism The most basic element of.
Chinese name
carbon atom
Foreign name
carbon
chemical formula
C
Melting point
About 3550 ℃ (diamond)
Boiling point
About 4827 ℃ (sublimation)
Appearance
solid state , black( graphite ), colorless( diamond
Atomic weight of element
twelve point zero one one
Proton number
six
Cycle
two
family
IVA
Electron layer distribution
2-4
Atomic volume
4.58 cm three /mol

physical property

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carbon Carbon
element Atomic weight :12.011
Period: 2
family :IVA
Electronic layer Distribution: 2-4
Atomic volume : 4.58
/mol
The arrangement of electrons in each energy level : 2,4
Oxidation value( oxide ): 4, 3, 2 (weak acid)
Color and appearance: black (graphite), colorless( diamond
Material state: solid
physical property Diamagnetism
melting point : about 3550 ℃ (diamond)
boiling point : about 4827 ℃ (sublimation)
Molar volume :5.29×10-6m3/mol
Element in In the sun Content of:( ppm ) 3000
Content of elements in seawater :(ppm) the pacific ocean Surface 23
Element content in the crust :(ppm)4800
Mohs hardness : graphite 1-2, diamond 10
Oxidized state : mainly - 4, C+2, C+4 (and other oxidation states)
Chemical bond Energy: (kJ/mol) C-H 411 C-C 348 C=C 614 C ∨ C 839 C=N 615 C ∨ N 891 C=O 745 C ∨ O 1074
Cell parameter : a = 246.4 pm b = 246.4 pm c = 671.1 pm α = 90° β = 90° γ = 120°
ionization energy :(kJ/ mol) M - M+ 1086.2 M+ - M2+ 2352 M2+ - M3+ 4620 M3+ - M4+ 6222 M4+ - M5+ 37827 M5+ - M6+ 47270 。
Elementary density :3.513 g/
(diamond), 2.260 g/
(Graphite, 20 ℃)
Electronegativity : 2.55 (Pauling scale)
specific heat :710 J/(kg·K)
conductivity : 0.061 × 10-6/(meter ohm)
Thermal conductivity :129 W/(m·K) First ionization energy 1086.5 kJ/mol second ionization energy 2352.6 kJ/mol The third ionization energy is 4620.5 kJ/mol The fourth ionization energy is 6222.7 kJ/mol The fifth ionization energy is 37831 kJ/mol The sixth ionization energy is 47277.0 kJ/mol.
Bonding : The carbon atom is generally tetravalent, which requires four single electrons, but ground state There are only two single electrons, so hybridization is always necessary when bonding. The most common way of hybridization is Sp3 hybrid , 4 valence electron Fully utilized, distributed in 4 tracks on average, belonging to equivalent hybridization
This structure is completely symmetrical and stable after bonding σ bond , and no Lone electron pair The repulsion is very stable. All carbon atoms in diamond are bonded in this hybrid way. alkane The carbon atom of is also in this category.
isotope : C12 C14 (Archaeological dating).
Structure: straight chain Branched chain and annular Structure.

isotope

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All carbon isotope Each atom of has six protons, but Neutron number Different (from 2 to 16). There are two natural carbon stable isotope : carbon-12( twelve C) Accounting for 98.93% of the earth's carbon, while carbon-13( thirteen C) Accounting for 1.07% of the rest. In organisms twelve C isotope The ratio is higher because biochemical reaction will selectively eliminate thirteen C. International Union of Pure and Applied Chemistry, 1961( IUPAC )It was decided to use the carbon-12 isotope as the definition standard of atomic weight unit. nuclear magnetic resonance What is detected is thirteen C。
Carbon-14 fourteen C) It's natural radio isotope , on earth abundance Is one part per trillion (0.0000000001%), mainly existing in atmosphere And surface mineral deposits, such as peat and others Organic matter Etc. Carbon-14 decays β − at 0.158 MeV energy due to half life It is only 5730 years old, so this isotope is almost extinct in ancient rocks, but it will be found in the upper atmosphere (lower stratosphere and higher stratosphere troposphere )Middle meridian cosmic rays And nitrogen. fourteen The abundance of C in the atmosphere and organisms is almost conservative, but it decreases regularly after the death of organisms, which is Radiocarbon dating Principle of. The dating method can measure carbon containing substances with a time length of less than 40000 years.
There are 15 known isotopes of carbon, including survival time The shortest is eight C, It will conduct proton emission and Alpha decay The half-life is 1.98739x10 − 21 seconds. isotope nineteen C has a halo effect, that is, its radius Specific density Uniform normal sphere Nucleus Much higher.