potassium sulphate

inorganic salt
Collection
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Potassium sulfate is a kind of inorganic salt , chemical formula is K two SO four , white crystalline powder. The appearance of agricultural potassium sulfate is mostly light yellow Hygroscopicity Small, not easy to caking, good physical properties, easy to use, good water-soluble potash fertilizer, and chlorine free nitrogen phosphorus , potassium ternary Compound fertilizer Main raw materials of. [1]
Chinese name
potassium sulphate [3]
Foreign name
Potassium sulphate
Potassium sulfate
chemical formula
K two SO four [3]
molecular weight
one hundred and seventy-four point two five nine [3]
CAS login number
7778-80-5 [3]
EINECS login number
231-915-5 [3]
Melting point
1067 ℃ [3]
Boiling point
1689 ℃ [3]
Water solubility
Soluble
Density
2.66 g/cm³ [3]
Appearance
White crystalline powder
Security description
S22;S24/25 [3]
crystal structure
Ionic crystal

Physical and chemical properties

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physical property

Melting point: 1067 ℃
Boiling point: 1689 ℃
Density: 2.66g/cm three
Potassium sulfate structure
Appearance: white crystalline powder

chemical property

Metathesis reaction : can react with soluble barium salt solution to form barium sulfate Sedimentation. [2]

Preparation method

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With sulfate type Potash mine And potassium salt lakes brine For raw materials. 98% sulfuric acid and potassium chloride The reaction is carried out at high temperature of 550 ℃ to directly produce potassium sulfate Hydrogen chloride , absorb with water, and produce hydrochloric acid as a by-product. This method is the main method for industrial production of potassium sulfate in China, called Mannham method. use Alunite It is obtained by reduction pyrolysis.
In Germany, potassium sulfate is mainly produced by the liquid phase reaction of magnesium sulfate ore and potassium chloride.
It is prepared by reaction of sulfuric acid and potassium chloride. Mixed sulfuric acid and Potassium hydroxide Potassium sulfate can also be obtained:
H two SO four + 2KOH = K two SO four + 2H two O

application area

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It is used to manufacture various potassium salts such as Potassium carbonate Potassium persulfate The basic raw materials of. Glass industry is used as settling agent. The dye industry is used as an intermediate. Spice industry is used as auxiliary agent. The pharmaceutical industry is also used as a laxative and to treat soluble barium salt poisoning. Potassium sulfate is a commonly used potash fertilizer in agriculture. The content of potassium oxide is 50%, commonly known as "Baikali" in Taiwan.

Calculate chemical data

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1. Drainage parameter calculation reference value (XlogP): 0
2. Number of hydrogen bond donors: 0 [3]
3. Number of hydrogen bond receptors: 4 [3]
4. Number of rotatable chemical bonds: 0 [3]
5. Number of tautomers: 0
6. Topological molecular polar surface area: 88.6 [3]
7. Number of heavy atoms: 7 [3]
8. Surface charge: 0 [3]
9. Complexity: 62.2 [3]
10. Number of isotope atoms: 0 [3]
11. Determine the number of atomic structure centers: 0 [3]
12. Number of uncertain atomic structure centers: 0 [3]
13. Determine the number of chemical bond structural centers: 0 [3]
14. Number of indeterminate chemical bond structure centers: 0 [3]
15. Number of covalent bond units: 3 [3]

toxicology data

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Acute toxicity: LD fifty : 4000mg/kg (rat oral); 4720mg/kg (rabbit percutaneous).
LC fifty :9400mg/m three , 2 hours (mice inhaled)

Safety terminology

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S22:Do not breathe dust.
Do not breathe dust
S24/25:Avoid contact with skin and eyes。
Avoid skin and eye contact;

Agricultural application

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Potassium sulfate is a colorless crystal with low hygroscopicity, difficult caking, good physical properties and easy application. It is a very good water-soluble potassium fertilizer. Potassium sulfate is also a chemical neutral, physiological acid fertilizer. Potassium sulfate is a chlorine free, high-quality and efficient potash fertilizer, especially in the planting of chlorine sensitive crops such as tobacco, grapes, sugar beets, tea trees, potatoes, flax and various fruit trees; It is also the main raw material of high-quality nitrogen, phosphorus and potassium ternary compound fertilizer.
Potassium sulfate type compound fertilizer is produced by the process of potassium chloride low-temperature conversion, chemical synthesis, and spray granulation. It has good stability. In addition to the three major nutrients N, P, and K necessary for plants, it also contains S, Ca, Mg, Zn, Fe, Cu, and other trace elements. This kind of fertilizer is suitable for various cash crops, especially for chlorine sensitive crops. The main component of potassium sulfate compound fertilizer is MAP( Monoammonium phosphate )And DAP( Diammonium phosphate )Ammonium sulfate (mainly obtained by neutralizing surplus sulfuric acid converted at low temperature with gaseous ammonia). Potassium sulfate urea And other impurities such as calcium sulfate phosphoric acid Fe, Al, Mg and a small amount of unreacted potassium chloride.
Precautions
First, in acid soil, excess sulfate will make the soil more acidic, and even increase the toxicity of active aluminum and iron in the soil to crops. Under flooding conditions, excessive sulfate will be reduced to generate hydrogen sulfide, which will make the roots black. Therefore, long-term application of potassium sulfate should be combined with farmyard manure, alkaline phosphate fertilizer and lime to reduce acidity. In practice, drainage and field drying measures should also be combined to improve ventilation.
Second, in calcareous soil, sulfate and calcium ions in the soil generate insoluble calcium sulfate (gypsum). Too much calcium sulfate will cause soil hardening, so attention should be paid to increasing farmyard manure.
Third, focus on the use of chlorine resistant crops, such as tobacco, tea trees, grapes, sugar cane, sugar beet, watermelon, potatoes, etc. Adding potassium sulfate not only improves the yield, but also improves the quality. The price of potassium sulfate is more expensive than that of potassium chloride, and the source of goods is less. It should be mainly used for economic crops that are sensitive to chlorine and like sulfur and potassium, and the benefits will be better.
Fourth, this kind of fertilizer is a physiological acid salt, which can reduce the soil PH value in alkaline soil.