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Dichlorodane

Organic compound
synonym Oat enemy (Oatmeal) generally refers to dichloromethane
Dichlorodane, also known as oat enemy, is an organic compound with the chemical formula C ten H seventeen Cl two NOS, Mainly used for pre broadcast herbicide The control effect of wild oats is up to 90%, and there is no adverse effect on wheat, highland barley, peas, potatoes, broad beans, rape and other crops.
On October 27, 2017, the list of carcinogens published by the International Agency for Research on Cancer of the World Health Organization (WHO) was preliminarily sorted out for reference. Dichlorodimetham was included in the list of category 3 carcinogens. [1]
Chinese name
Dichlorodane
Foreign name
Diallate
Alias
Oat enemy
chemical formula
C ten H seventeen Cl two NOS
molecular weight
two hundred and seventy point two one nine
CAS login number
2303-16-4
EINECS login number
218-961-1
Melting point
25 to 30 ℃
Boiling point
306 ℃
Density
1.18 g/cm³
Appearance
Brown liquid
Security description
S25;S36/37;S60;S61
Hazard symbol
Xn;N
Hazard description
R22;R40;R50/53

Physical and chemical properties

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Density: 1.18g/cm three
Melting point: 25-30 ℃
Boiling point: 306 ℃
Flash point: > 100 ° C [3]
Refractive index: 1.52
Steam pressure: 0.000791mmHg at 25 ° C
Appearance: brown liquid
Solubility: miscible with acetone, ethanol, ethyl acetate, kerosene, xylene and other organic solvents [2]

Molecular structure data

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Molar refractive index: 69.64
Molar volume (cm three /mol):228.8
Isotonic specific volume (90.2K): 566.4
Surface tension (dyne/cm): 37.5
Polarization (10 -24 cm three ):27.6 [2]

Calculate chemical data

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Reference value for drainage parameter calculation (XlogP): 3.6
Number of hydrogen bond donors: 0
Number of hydrogen bond receptors: 2
Number of rotatable chemical bonds: 5
Number of tautomers: 0
Topological molecular polar surface area: 45.6
Number of heavy atoms: 15
Surface charge: 0
Complexity: 234
Number of isotope atoms: 0
Determine the number of atomic structure centers: 0
Number of uncertain atomic structure centers: 0
Determine the number of chemical bond stereocenters: 1
Number of uncertain chemical bond structure centers: 0
Number of covalent bond units: 1 [2]

purpose

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It is mainly used as a pre sowing herbicide, with the control effect of wild oats up to 90%, and has no adverse effect on wheat, highland barley, peas, potatoes, broad beans, rape and other crops.

Emergency Management

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Leakage emergency treatment

Evacuate the personnel in the leakage contaminated area to the safety area, prohibit irrelevant personnel from entering the contaminated area, and suggest that emergency personnel wear self-contained breathing apparatus and chemical protective clothing. Do not directly contact the leakage, absorb it with sand, shovel it into the bucket, and pour it into an open place for deep burial. Lime shall be sprinkled on the polluted area and washed with a large amount of water. The diluted sewage shall be discharged into the wastewater system. In case of a large amount of leakage, the dike shall be used to collect it, and then it shall be collected, transferred, recycled or discarded after harmless treatment.

Protective measures

Respiratory system protection: gas mask must be worn during production operation or agricultural use. Self contained breathing apparatus shall be worn during emergency rescue or escape.
Eye protection: wear chemical safety goggles.
Protective clothing: wear corresponding protective clothing.
Hand protection: wear chemical resistant gloves.
Others: Smoking, eating and drinking are prohibited at the work site. After work, take a shower and change clothes. Pay attention to personal hygiene. Pre employment and regular physical examination shall be carried out.

First aid measures

Skin contact: Rinse thoroughly with soapy water and clean water. Get medical attention.
Eye contact: open the eyelids and flush with flowing water for 15 minutes. Get medical attention.
Inhalation: leave the site to fresh air. Get medical attention.
Ingestion: Drink moderate amount of warm water to induce vomiting if taken by mistake. Get medical attention.

security information

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Safety terminology

S25:Avoid contact with eyes.
Avoid eye contact.
S36/37:Wear suitable protective clothing and gloves.
Wear appropriate protective clothing and gloves.
S60:This material and/or its container must be disposed of as hazardous waste.
The substance and its container must be disposed of as hazardous waste.
S61:Avoid release to the environment. Refer to special instructions/Safety data sheets.
To avoid release into the environment, refer to special instructions/safety receipt instructions.

Risk terminology

R22:Harmful if swallowed.
It is harmful if swallowed.
R40:Possible risks of irreversible effects.
There may be risk of irreversible effects.
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
It is extremely toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.