Neopentane

Organic compound
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synonym Pentane (Neopentane) generally refers to neopentane
Neopentane, also known as 2,2-dimethylpropane, is an organic compound with the chemical formula C five H twelve It is a colorless gas under normal temperature and pressure, and a highly volatile liquid under standard conditions. Neopentane is insoluble in water, but soluble in ethanol, ether, carbon tetrachloride, etc. Gas mixed with air, explosion limit 1.4~7.5% (volume), mainly used for preparing butyl rubber. [1]
Chinese name
Neopentane
Foreign name
Neopentane
Alias
2,2-dimethylpropane
chemical formula
C five H twelve
molecular weight
seventy-two point one four nine
CAS login number
463-82-1
EINECS login number
207-343-7
Melting point
-19.5 ℃
Boiling point
9.5 ℃
Water solubility
Insoluble
Density
0.649 g/cm³ [4]
Appearance
Colourless gas
Security description
S9;S16;S33;S61
Hazard symbol
F+;N
Hazard description
R12;R51/53

Physical and chemical properties

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Density: 2.951kg/m three
Melting point: - 19.5 ℃
Boiling point: 9.5 ℃
Refractive index: 1.37
Steam pressure: 1420mmHg at 25 ° C
Critical temperature: 160.6 ℃
Critical pressure: 3.20MPa
Upper explosive limit( V / V ):7.5%
Upper explosive limit( V / V ):1.4%
Appearance: colorless gas
Solubility: insoluble in water, soluble in ethanol, ether, carbon tetrachloride, etc

Preparation method

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It can be obtained by reacting tert butyl chloride with methyl magnesium chloride. [2]

purpose

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Mainly used for manufacturing butyl rubber. [2]

Molecular structure data

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Molar refractive index: 25.17
Molar volume (cm three /mol):111.1
Isotonic specific volume (90.2K): 226.1
Surface tension (dyne/cm): 17.1
Polarization (10 -24 cm three ):9.98 [2]

Calculate chemical data

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Reference value for drainage parameter calculation (XlogP): 2.5
Number of hydrogen bond donors: 0
Number of hydrogen bond receptors: 0
Number of rotatable chemical bonds: 0
Number of tautomers: none
Topological molecular polar surface area: 0
Number of heavy atoms: 5
Surface charge: 0
Complexity: 15.5
Number of isotope atoms: 0
Determine the number of atomic structure centers: 0
Number of uncertain atomic structure centers: 0
Determine the number of chemical bond structure centers: 0
Number of uncertain chemical bond structure centers: 0
Number of covalent bond units: 1 [2]

toxicology data

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1. Acute toxicity: LD fifty : 100mg/kg (mouse abdominal cavity)
2. Subacute and chronic toxicity: rats, exposed to 800mg/m all day three For 117 consecutive days, there was no change in activity and weight.
3. Others: LCLo: 1097000mg/m three (Inhaled by mice) [4]

Storage method

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It shall be stored in a cool and ventilated special warehouse for flammable gas. Keep away from kindling and heat sources. The warehouse temperature should not exceed 30 ℃. Keep container sealed. It shall be stored separately from oxidant and shall not be mixed. Explosion proof lighting and ventilation facilities shall be adopted. It is prohibited to use mechanical equipment and tools that are easy to generate sparks. The storage area shall be equipped with leakage emergency treatment equipment. [2]

Emergency treatment

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Leakage emergency treatment

Evacuate the personnel in the leakage contaminated area to the windward place quickly, isolate them, and strictly restrict access. Cut off the ignition source. It is recommended that emergency personnel wear self-contained positive pressure respirators and fire protection clothing. Cut off the leakage source as much as possible. In case of gas, cover the sewer and other places near the leakage point with industrial coating or adsorption/absorbent to prevent gas from entering. Reasonable ventilation to accelerate diffusion. Dilute with spray water. Or it can be led to the furnace or burned in the depression by pipeline. If there is no danger, burn on the spot, and spray water to cool the surroundings to prevent other combustibles from catching fire. Leaking containers shall be properly treated, repaired and inspected before reuse. If it is liquid, prevent it from entering into restricted spaces such as sewers and flood discharge ditches.
Small amount of leakage: absorb or absorb with sand or other incombustible materials.
Large amount of leakage: build a dike or dig a pit to receive; Cover with foam to reduce steam disaster. Use explosion-proof pump to transfer to tank car or special collector for recycling or transport to waste disposal site.

Protective measures

Respiratory system protection: generally, no special protection is required, and self inhalation filter gas mask (half mask) can be worn in case of high concentration contact.
Eye protection: Generally, no special protection is required, and chemical safety goggles can be worn in case of high concentration contact.
Body protection: Wear anti-static work clothes.
Hand protection: wear general operation protective gloves.
Others: Smoking is strictly prohibited at the work site. Avoid high concentration inhalation. When entering tanks, confined spaces or other high concentration areas for operation, someone must supervise.

First aid measures

Skin contact: Take off the contaminated clothes and wash the skin thoroughly with soapy water and clean water.
Eye contact: Lift the eyelid and flush with flowing water or physiological saline. Get medical attention.
Inhalation: quickly leave the site to a place with fresh air. Keep the respiratory tract unobstructed. If breathing is difficult, give oxygen. If breathing stops, perform artificial respiration immediately. Get medical attention.
Ingestion: drink enough warm water, induce vomiting, and seek medical advice.
Extinguishing method: cut off the gas source. If the gas source cannot be cut off immediately, it is not allowed to extinguish the burning gas. Spray water to cool the container, and move the container from the fire site to an open place if possible.
Extinguishing agent: spray water, foam, carbon dioxide, dry powder. [3]

security information

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Safety terminology

S9:Keep container in a well-ventilated place.
Keep the container in a well ventilated place.
S16:Keep away from sources of ignition - No smoking.
Keep away from ignition sources and no smoking.
S33:Take precautionary measures against static discharges.
Take precautions against static electricity.
S61:Avoid release to the environment. Refer to special instructions/Safety data sheets.
Avoid releasing into the environment, refer to special instructions/safety receipt instructions.

Risk terminology

R12:Extremely flammable.
Extremely flammable.
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
It is toxic to aquatic organisms and may cause long-term adverse effects in the aquatic environment.