Ethylene glycol dimethyl ether

Organic compound
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Ethylene glycol dimethyl ether, also known as 1,2-dimethoxyethane, is an organic compound with molecular formula C four H ten O two , a colorless transparent liquid, soluble in water, ethanol and hydrocarbons, is mainly used in polymer chemistry, electrochemistry, boron chemistry process fields, as well as as solvent for resin, nitrocellulose, pharmaceutical extractant, and organic synthesis intermediate.
Chinese name
Ethylene glycol dimethyl ether [2]
Foreign name
1,2-Dimethoxyethane [2]
Alias
1,2-Dimethoxyethane [2]
chemical formula
C four H ten O two [2]
molecular weight
ninety point one two one [2]
CAS login number
110-71-4 [2]
EINECS login number
203-794-9 [2]
Melting point
-58 ℃
Boiling point
82 to 83 ℃
Water solubility
soluble
Appearance
colorless liquid
Flash point
-2 ℃ (CC)
Security description
S45;S53 [2]
Hazard symbol
F [2]
Hazard description
R11;R19;R20;R60;R61 [2]
MDL No
MFCD00008502
RTECS No
KI1451000
BRN No
one million two hundred and nine thousand two hundred and thirty-seven
PubChem No
twenty-four million eight hundred and fifty-five thousand seven hundred and twelve

Physical and chemical properties

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Appearance: colorless liquid
Melting point: - 58 ℃
Boiling point: 82-83 ℃
Density: 0.867 g/mL at 25 ° C (lit.)
Flash point: - 2 ℃ (CC)
Refractive index: 1.379 (20 ℃)
Saturated vapor pressure: 6.40kPa (20 ℃) [2]
Critical temperature: 263 ℃ [2]
Critical pressure: 3.87MPa [2]
Ignition temperature: 202 ℃ [2]
Upper explosive limit( V / V ):18.7% [2]
Lower explosive limit( V / V ):1.9% [2]
Solubility: soluble in water, ethanol and hydrocarbon

Molecular structure data

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Molar refractive index: 24.07 [2]
Molar volume (cm three /mol):1107.2 [2]
Isotonic specific volume (90.2K): 230.6 [2]
Surface tension (dyne/cm): 21.3 [2]
Polarization (10 -24 cm three ):9.54 [2]

Calculate chemical data

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Reference value for drainage parameter calculation (XlogP): None
Number of hydrogen bond donors: 0 [2]
Number of hydrogen bond receptors: 2 [2]
Number of rotatable chemical bonds: 3 [2]
Number of tautomers: 0
Topological molecular polar surface area: 18.5 [2]
Number of heavy atoms: 6 [2]
Surface charge: 0 [2]
Complexity: 17.5 [2]
Number of isotope atoms: 0 [2]
Determine the number of atomic structure centers: 0 [2]
Number of uncertain atomic structure centers: 0 [2]
Determine the number of chemical bond structure centers: 0 [2]
Number of uncertain chemical bond structure centers: 0 [2]
Number of covalent bond units: 1 [2]

toxicology data

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Acute toxicity: oral LC in mice fifty :3200mg/kg; Rat oral LD fifty :>5000mg/kg; Rabbit oral LD fifty :320mg/kg; Oral LDLo of rats: 1000mg/kg; Rat skin LD fifty :5370mg/kg; Rabbit skin LDLo: 2000 mg/kg; Rats inhaled LDLo: 63mg/m three /6h。

Storage method

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Generally, the commodity is added with stabilizer. Store in a cool and ventilated warehouse. Keep away from kindling and heat sources. The warehouse temperature should not exceed 37 ℃, and the packaging should be sealed, and should not be in contact with the air. It shall be stored separately from oxidants and acids, and mixed storage is strictly prohibited. Explosion proof lighting and ventilation facilities shall be adopted. It is prohibited to use mechanical equipment and tools that are easy to generate sparks. The storage area shall be equipped with leakage emergency treatment equipment and appropriate materials. [1]

purpose

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It is mainly used in polymer chemistry, electrochemistry, boron chemical process fields, as well as solvent for resin, nitrocellulose, pharmaceutical extractant, and organic synthesis intermediate.

Fire fighting measures

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Inflammable, easy to cause combustion and explosion in case of open fire and high heat. It can react strongly with oxidants. Peroxides with potential explosion risk may be generated when exposed to air or under light conditions. Its vapor is heavier than air, and can spread to a considerable distance at a lower place. It will ignite and recoil when encountering an ignition source.
Move the container from the fire site to an open place as far as possible. Spray water to keep the fire site container cool until the fire is extinguished. If the container in the fire site has changed color or sounds from the safety relief device, it must be evacuated immediately. Extinguishing agent: insoluble foam, dry powder, carbon dioxide, sand.

Leakage emergency treatment

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Evacuate the personnel in the leakage contaminated area to a safe area quickly, isolate them, and strictly restrict access. Cut off the ignition source. It is recommended that emergency personnel wear self-contained positive pressure respirators and anti-static work clothes. Cut off the leakage source as much as possible. Prevent from flowing into restricted spaces such as sewers and flood discharge ditches.
Small amount of leakage: absorb with activated carbon or other inert materials. A large amount of water can also be used for flushing, and the diluted washing water will be discharged into the waste water system.
Large amount of leakage: build a dike or dig a pit to receive. Cover with foam to reduce steam disaster. Use explosion-proof pump to transfer to tank car or special collector for recycling or transport to waste disposal site.

First aid measures

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Skin contact: Take off the contaminated clothes and wash the skin thoroughly with soapy water and clean water.
Eye contact: Lift the eyelid and flush with flowing water or physiological saline. Get medical attention.
Inhalation: quickly leave the site to a place with fresh air. Keep the respiratory tract unobstructed. If breathing is difficult, give oxygen. If breathing stops, perform artificial respiration immediately. Get medical attention.
Ingestion: drink enough warm water to induce vomiting. Get medical attention.

security information

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Safety terminology

S45:In case of accident or if you feel unwell, seek medical advice immediately (show the lable where possible).
In case of an accident or feeling unwell, seek medical advice immediately (show the label if possible).
S53:Avoid exposure - obtain special instructions before use.
Avoid contact and obtain special instructions before use.

Risk terminology

R11:Highly flammable.
Highly flammable.
R19:May form explosive peroxides.
Explosive peroxides may be generated.
R20:Harmful by inhalation.
Harmful by inhalation.
R60:May impair fertility.
May impair fertility.
R61:May cause harm to the unborn child.
May cause harm to unborn babies.