Collection
zero Useful+1
zero

Paraldehyde

chemical substances
Triacetaldehyde, also known as triacetaldehyde and paracetaldehyde, is an organic compound with the chemical formula C six H twelve O three , is, mainly used as solvent and organic synthesis.
Chinese name
Paraldehyde
Foreign name
paraldehyde
Alias
Paracetaldehyde Triacetaldehyde
chemical formula
C six H twelve O three
molecular weight
one hundred and thirty-two point one five nine
CAS login number
123-63-7
EINECS login number
204-639-8
Melting point
12 ℃
Boiling point
65 to 82 ℃
Water solubility
soluble
Density
0.994 g/cm³
Appearance
Colorless oily liquid
Flash point
35.5 ℃ (OC)
Security description
S9;S16;S29;S33
Hazard symbol
F
Hazard description
R11
MDL No
MFCD00036208
RTECS No
YK0525000
BRN No
eighty thousand one hundred and forty-two
PubChem No
twenty-four million eight hundred and ninety-eight thousand six hundred and sixty-two

Physical and chemical properties

Announce
edit
Density: 0.994g/cm three
Melting point: 12 ℃
Boiling point: 65-82 ℃
Flash point: 35.5 ℃ (OC)
Refractive index: 1.39 (20 ℃)
Critical temperature: 290 ℃
Critical pressure: 3.5MPa
Ignition temperature: 235 º C
Saturated vapor pressure: 3.36kPa (20 º C)
Upper explosive limit( V / V ):17%
Lower explosive limit( V / V ):1.3%
Appearance: colorless oily liquid
Solubility: soluble in water, miscible in most organic solvents [1]

Molecular structure data

Announce
edit
Molar refractive index: 30.47
Molar volume (cm three /mol):88.6
Isotonic specific volume (90.2K): 241.4
Surface tension (dyne/cm): 54.9
Polarization (10 -24 cm three ):12.08 [1]

Calculate chemical data

Announce
edit
Reference value for drainage parameter calculation (XlogP): None
Number of hydrogen bond donors: 0
Number of hydrogen bond receptors: 3
Number of rotatable chemical bonds: 0
Number of tautomers: 0
Topological molecular polar surface area: 27.7
Number of heavy atoms: 9
Surface charge: 0
Complexity: 63.3
Number of isotope atoms: 0
Determine the number of atomic structure centers: 0
Number of uncertain atomic structure centers:: 0
Determine the number of chemical bond structure centers: 0
Number of uncertain chemical bond structure centers: 0
common Price key unit quantity: 1 [1]

toxicology data

Announce
edit
1. Acute toxicity
LD fifty : 1530mg/kg (rat by mouth); 14000mg/kg (rabbit percutaneous).
2. Irritation
Rabbit percutaneous: 500mg, mild stimulation (open stimulation test)
Rabbit eye: 5mg, severe irritation.
3. Mutagenicity
Cytogenetic analysis: Saccharomyces cerevisiae 50mmol/tube. [1]

purpose

Announce
edit
Mainly used as solvent and organic synthesis.

Emergency Management

Announce
edit

Leakage emergency treatment

Evacuate the personnel in the leakage contaminated area to a safe area quickly, isolate them, and strictly restrict access. Cut off the ignition source. It is recommended that emergency personnel wear self-contained positive pressure respirators and fire protection clothing. Cut off the source of leakage as far as possible to prevent it from entering into restricted spaces such as sewers and flood discharge ditches.
Small amount of leakage: absorb or absorb with sand or other incombustible materials.
Large amount of leakage: build a dike or dig a pit to receive; Cover with foam to reduce steam disaster. Spray water cools and dilutes steam, protects on-site personnel, and dilutes leakage into incombustible materials. Use explosion-proof pump to transfer to tank car or special collector for recycling or transport to waste disposal site.

Protective measures

Respiratory system protection: When the concentration in the air exceeds the standard, you should wear a self-priming filter gas mask (half mask). Wear air respirator during emergency rescue or evacuation.
Eye protection: wear safety glasses.
Body protection: Wear anti-static work clothes.
Hand protection: wear benzene and oil resistant gloves.
Others: Smoking, eating and drinking are strictly prohibited at the work site. After work, take a bath and change clothes. Keep good hygiene habits.

First aid measures

Skin contact: Take off the contaminated clothes and wash the skin thoroughly with soapy water and clean water.
Eye contact: Lift the eyelid and flush with flowing water or physiological saline. Get medical attention.
Inhalation: quickly leave the site to a place with fresh air. Keep the respiratory tract unobstructed. If breathing is difficult, give oxygen. If breathing stops, perform artificial respiration immediately. Get medical attention.
Ingestion: drink enough warm water, induce vomiting, and seek medical advice.

security information

Announce
edit

Safety terminology

S9:Keep container in a well-ventilated place.
Keep the container in a well ventilated place.
S16:Keep away from sources of ignition - No smoking.
Keep away from ignition sources and no smoking.
S29:Do not empty into drains.
Do not discharge into the sewer.
S33:Take precautionary measures against static discharges.
Take precautions against static electricity.

Risk terminology

R11:Highly flammable.
Highly flammable.