Ammonium carbonate

inorganic salt
Collection
zero Useful+1
zero
synonym (nh4)2co3 ((nh4) 2co3) generally refers to ammonium carbonate
Ammonium carbonate is a kind of inorganic compound , the chemical formula is (NH four ) two CO three It is a colorless cubic crystal, easily soluble in water, and the aqueous solution is alkaline, insoluble in ethanol carbon disulfide and Concentrated ammonia water Unstable to light and heat, slightly hygroscopic.
Chinese name
Ammonium carbonate [4]
Foreign name
Ammonium carbonate [4]
chemical formula
(NH four ) two CO three
molecular weight
ninety-six point zero eight six [4]
CAS login number
506-87-6 [4]
EINECS login number
208-058-0
Melting point
58 ℃ [4]
Water solubility
Soluble
Density
1.50 kg/m³
Appearance
White powder
Security description
S24/25
Hazard symbol
Xn [4]
Hazard description
R22;R52/53
UN dangerous goods number
nine thousand and eighty-four [4]
Regulatory information
This product is not controlled
Storage
Sealed, cool and dark storage

Physical and chemical properties

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physical property

Melting point: 58 ℃
Density: 1.50g/cm three
logP:0.546
Refractive index: 1.4616
Steam pressure: 2.58E-05mmHg at 25 ° C
Appearance: white powder
Solubility: soluble in water, insoluble in ethanol, carbon disulfide and concentrated ammonia water.

chemical property

1. Obvious decomposition at room temperature:
2. Reaction with acid:
3. Reaction with alkali: [5 ]
4. React with some salts:

Preparation method

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1. By ammonia And carbon dioxide It is cooled and crystallized by water:
2. By ammonium sulphate And calcium carbonate The suspension of
3. Urea will gradually react with water in aqueous solution to produce ammonium carbonate:

application area

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1. Drip analysis lithium radium and thorium And carbonate synthesis. It is also used as fertilizer, fire extinguishing agent, detergent, medicine, rubber, fermentation and other industries.
2. It is used as raw material of fermentation powder, various ammonium salts, buffer, printing and dyeing auxiliary, fertilizer and analytical reagent.
3. Edible ammonium carbonate is used as buffer, neutralizer, leavening agent and fermentation promoter (for making wine).
4. Ammonium carbonate is used in sulfosalicylic acid silver plating electrolyte, but heavy metals, sulfur and Thiocyanate Otherwise, the anode is easy to blacken. In addition, ammonium carbonate is also used to remove cadmium nickel And other plating solutions.

Molecular structure data

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1. Molar refractive index: 9.78
2. Molar volume (cm three /mol):37.1
3. Isotonic specific volume (90.2K): 110.4
4. Surface tension (dyne/cm): 77.9
5. Polarization (10 -24 cm three ):3.87 [2]

Calculate chemical data

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1. Reference value for drainage parameter calculation (XlogP): None
2. Number of hydrogen bond donors: 3 [4]
3. Number of hydrogen bond receptors: 4 [4]
4. Number of rotatable chemical bonds: 0 [4]
5. Number of tautomers:
6. Topological molecule polar surface area (TPSA): 58.5 [4]
7. Number of heavy atoms: 5 [4]
8. Surface charge: 0 [4]
9. Complexity: 26.3 [4]
10. Number of isotope atoms: 0 [4]
11. Determine the number of atomic structure centers: 0 [4]
12. Number of uncertain atomic structure centers: 0 [4]
13. Determine the number of chemical bond structure centers: 0 [4]
14. Number of uncertain chemical bond structure centers: 0 [4]
15. Number of covalent bond units: 2 [1]

toxicology data

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acute toxicity
Intravenous LD in mice fifty : 96mg/kg, convulsion or epilepsy, respiratory irritation;
Intravenous LDLo in dogs: 200 mg/kg;
Rabbit subcutaneous LDLo: 900mg/kg;
Rabbit intravenous LDLo: 200 mg/kg;
Rabbit transrectal LDLo: 800mg/kg;
Frog subcutaneous LDLo: 250mg/kg;
Frog parenteral LDLo: 758mg/kg.

security information

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Dangerous goods mark: Xn
Hazard category code: 22-52, 53
Safety instructions: 24/25
Transport No. of dangerous goods: UN 9084
WGK Germany:1
RTECS:BP1925000 [3]

Storage and transportation conditions

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1. Store in a cool, dry and well ventilated warehouse. Keep away from kindling and heat sources. Protect from direct sunlight. Packing and sealing.
2. It shall be stored separately from acids and edible chemicals, and mixed storage is strictly prohibited. The storage area shall be equipped with appropriate materials to contain leakage.