############################################################################### ##本CIF包含了一篇论文中的数据，该论文将于##《晶体学报》第C节。它符合##《晶体学学报》C版作者须知##由IUCr期刊委员会主持的同行评审## ##结晶信息文件格式的完整详细信息##论文“结晶信息文件（CIF）：##S.R.Hall，F.H##艾伦和I.D.布朗【《水晶学报》（1991），A47655-685】## ##核心CIF词典的当前版本可从以下网址获得：## ftp://ftp.iucr.org/pub/cif_core.dic。## ##软件可免费用于结构的图形显示##CIF价格。有关信息，请参阅CIF软件页面## http://www.iucr.org/resources/cif/software。 ## ##此文件可用于##科学界，只要对该杂志给予适当的归属#从中获得它的物品## ###############################################################################数据_I_审计_创建_方法SHELXL2013_数据库_code_depnum_ccdc_archive“ccdc 1013352”_化学名称系统；锡化钙金；_化学名称通用？_化学配方奶粉？_化学公式“Au-Ca-Sn”_化学式‘Ca-Au-Sn’_化学配方重量355.74_化学熔点？_货架空间组注释；这种shelxl细化所采用的对称性是唯一定义的由以下循环执行，该循环应始终用作对称信息优先于上述空间组名称。它们仅用作注释。；_空间群晶体系统正交_space_group_name_H-M_alt“I M 2”_space_group_name_调用“I 2-2”回路__空间组符号操作'x，y，z''-x，-y，z'“x，-y，z”“-x，y，z”“x+1/2，y+1/2，z+1/2”“-x+1/2，-y+1/2，z+1/2”“x+1/2，-y+1/2，z+1/2”‘-x+1/2，y+1/2，z+1/2’_单元格长度a 4.5261（7）_单元格长度b 7.1356（11）_单元格长度c 7.8147（11）_单元格字母90_单元格_单元格_贝塔90_单元格角度伽马90_单元格_卷252.39（7）_单元格_公式_单位_Z 4_单元格_测量_刷新_使用330_细胞测量时间最小值3.867_单元格_测量_高度_最大值28.178_单元格_测量_温度273（2）_exptl_crystal_description不规则_exptl晶体有色金属漆_exptl_crystal_size最大值0.028_exptl_晶体_尺寸_内径0.024_exptl晶体尺寸最小0.019_exptl晶体密度衍射9.362_exptl晶体密度测量？_exptl晶体密度方法？_exptl_晶体_F_000 596_出口_吸收_效率_mu 69.576_exptl_absorpt_correction_type经验性_exptl_absorpt_process_details“（SADABS；Sheldrick，1996）”_货架_估计_吸收T_min？_货架_估计_吸收T_max？_exptl_absorpt_correction_T_最小0.16_exptl_吸收_修正_最大值0.27_exptl_special_details？_衍射环境温度273（2）_衍射_辐射_类型MoK\a_衍射辐射波长0.71073_diffrin_measurement_device_type“Bruker SMART APEXII CCD区域探测器”_衍射测量方法_衍射检测器面积平均值？_衍射_反射_编号769_diffren_refns_av_R等效物0.0239_衍射_refns_theta_min 3.867_衍射_反射_热最大值28.178_diffrin_refns_theta完整25.242_衍射_测量_分数_热_最大值0.946_衍射_测量_分数_高度_满1.000_衍射反射极限h最小值-5_衍射反射极限h最大值5_衍射_反射_极限_k最小值-4_衍射反射极限k最大值9_衍射_反射_极限_最小值-10_差异_限制_最大值9_精化_特殊细节；精炼为反转孪晶。；_refns_number_total参考号_总计330_refns_number_gt参考号326_refns_threshold_expression I>2\s（I）_细分_ls_structure_factor_cef Fsqd_refine_ls_matrix_type已满_refine_ls_R_因子_全部0.0280_细化_ls_R_系数_gt 0.0276_细化_ls_wR_factor_gt 0.0719_细化_ls_wR_factor_ref 0.0720_精炼_ls_goodness_of_fit_ref 1.173_细化_限制_全部1.171_细化_ls_number_reflns 330_细化ls_number_parameters 23_细化_ls_number_restraints 1_细化ls_hydrogen_treaction。_细化_权重_方案计算_细化_权重_详细信息'w=1/[\s^2^（Fo^2^）+（0.0360P）^2^+7.6305P]其中P=（Fo^2 ^+2Fc^2 ^）/3'_atom_sites_solution_hydrogens。_atom_sites_solution_primary直接_atom_sites_solution_secondary差异映射_精细_偏移/su_最大0.000_细化_ls_shift/su平均值0.000_精制密度最大值2.675_精化偏差最小值-1.851_refine_ls_extinction_method“SHELXL2013（Sheldrick，2008）”_refine_ls_extinction_cef 0.0072（10）_细化_ls_extinction_expression'Fc^*^=kFc[1+0.001xFc^2^\l^3^/sin（2\q）]^-1/4^'_细化_ls_abs_structure_details“精炼为反转孪晶（Flack，1983）”_refine_ls_abs_structure_Flack 0.31（3）回路__原子类型符号_原子类型描述_atom_type_scat_dispersion_real格式_atom_type_scat_dispersion_imag_原子类型类别源“钙”“钙”0.2262 0.3064“国际表格C卷表4.2.6.8和6.1.1.4”“锡”-“锡”-0.6537 1.4246“国际表格C卷表4.2.6.8和6.1.1.4”“金”“金”-2.0133 8.8022“国际表格C卷表4.2.6.8和6.1.1.4”_computing_data_collection“SMART（Bruker，2002）”_computing_cell_refinement“SAINT-Plus（Bruker，2013）”_computing_data_reduction“SAINT-Plus（Bruker，2013）”_computing_structure_solution“SHELXS97（Sheldrick，2008）”_computing_structure_refinement“SHELXL2013（Sheldrick，2008）”_computing_molecular_graphics“钻石（勃兰登堡，2000）”_computing_publication_material“SHELXTL2013（Sheldrick，2008）”回路__原子站点类型符号_原子站点标签_原子站点分形x_原子站点分形_原子站点分数z_原子_站点_U_iso_or_equiv_原子站点地址类型_原子网站地址标签_原子位置占用_atom_site监控程序集_原子站点监控程序组金金0.0000 0.21650（14）0.68259（7）0.0106（5）单位。锡锡0.0000 0.3076（4）0.0130（3）0.0163（6）单位。钙Ca1 0.5000 0.5000 0.8058（15）0.0083（18）Uani d 1。钙钙0.0000 0.5000 0.3876（16）0.0109（19）单位。回路__原子网站标签_原子_现场_日产_U_11_原子_现场_日产_U_22_原子_地点_尼索_U_33_原子_现场_日产_U_12_原子_位置_同位素_U_13_原子_现场_日产_U_23金0.0111（6）0.0074（6）0.0133（6）.000 0.000 0.0007（7）锡0.0145（14）0.0191（10）0.0153（13）0.000 0.000 0.0004（9）钙0.010（5）0.006（4）0.009（4）.000 0.000 0.000钙0.014（6）0.007（4）0.012（5）0.000 0.000_地理_特殊_详细信息；所有e.s.d.（两个l.s.平面之间二面角的e.s.d.除外）使用全协方差矩阵进行估计在估计e.s.d.的距离、角度时单独考虑和扭转角；e.s.d.细胞内参数之间的相关性仅为当它们由晶体对称性定义时使用。近似（各向同性）细胞e.s.d.的处理用于估计涉及l.s.的e.s.d。飞机。；回路__地理绑定原子站点标签1_地理绑定原子站点标签2_地理绑定站点对称2_地理绑定距离_geom_bond_publ标志Au-Sn 6_455 2.6282（13）？金锡6 2.6282（13）？金锡1_556 2.663（3）？金钙合金。3.067(9) ?金-金2 3.090（2）？金Ca2 5_545 3.174（6）？Au-Ca2 5_445 3.174（6）？金Ca1 1_455 3.185（4）？金钙合金。3.185(4) ?金Ca1 5_444 3.325（11）？锡金6_554 2.6282（13）？锡金6_454 2.6282（13）？锡金合金1_554 2.663（3）？锡锡2_565 2.746（5）？锡Ca1 1_454 3.103（7）？锡Ca1 1_554 3.103（7）？锡钙合金_444 3.171（9）？锡钙合金。3.233(12) ?Sn Ca25_444 3.301（4）？锡钙合金5_544 3.301（4）？Ca1锡2_666 3.103（7）？Ca1锡1_656 3.103（7）？Ca1锡1_556 3.103（7）？Ca1锡2_566 3.103（7）？Ca1 Sn 6 3.171（9）？Ca1 Sn 5 3.171（9）？Ca1 Au 2_665 3.185（4）？Ca1 Au 2_565 3.185（4）？Ca1 Au 1_655 3.185（4）？Ca1 Au 5 3.325（11）？Ca1 Au 6 3.325（11）？Ca2 Au 2_565 3.067（9）？Ca2 Au 6_454 3.174（6）？Ca2 Au 5_554 3.174（6）？Ca2 Au 5_454 3.174（6）？Ca2-Au 6_554 3.174（6）？钙锡2_565 3.233（12）？Ca2 Sn 5 3.301（4）？Ca2 Sn 6_455 3.301（4）？Ca2 Sn 6 3.301（4）？Ca2-Sn 5_455 3.301（4）？回路__地理角度_高程_高程_标注_1_地理角度原子站点标签2_地理角度原子站点标签3_地理角度场地对称1_地理角度场地对称3_地理角度_地理角度ubl标志锡金锡6_455 6 118.87（9）？锡金锡6_455 1_556 120.33（5）？锡金锡6 1_556 120.33（5）？Sn-Au-Ca2 6_455。70.38(8) ?锡金钙合金6。70.38(8) ?锡金Ca2 1_556。124.60(17) ?锡金金6_455 2 86.25（6）？锡-金-金6 2 86.25（6）？锡金Au 1_556 2 104.13（6）？Ca2-Au-Au。2 131.27(15) ?锡金钙6_455 5_545 146.78（8）？锡-金Ca26 5_545 66.97（18）？锡金Ca2 1_556 5_545 68.2（2）？Ca2 Au Ca2。5_545 134.46(14) ?金-金-钙2 5_545 60.88（7）？锡金钙6_455 5_445 66.97（18）？锡金钙6 5_445 146.78（8）？锡金Ca2 1_556 5_445 68.2（2）？Ca2 Au Ca2。5_445 134.46(14) ?Au-Au Ca2 5_445 60.88（7）？Ca2 Au Ca2 5_545 5_445 91.0（2）？锡金Ca1 6_455 1_455 65.30（16）？Sn-Au-Ca1 6 1_455 143.71（12）？锡金Ca1 1_556 1_455 63.4（2）？Ca2 Au Ca1。1_455 78.95(14) ?Au Au Ca1 2 1_455 129.44（6）？Ca2 Au Ca1 5_545 1_455 131.5（4）？Ca2 Au Ca1 5_445 1_455 69.50（12）？Sn-Au-Ca1 6_455。143.71(12) ?锡金钙16。65.30(16) ?锡金Ca1 1_556。63.4(2) ?Ca2 Au Ca1。78.95(14) ?金-金-钙1 2。129.44(6) ?Ca2 Au Ca1 5_545。69.50(12) ?Ca2 Au Ca1 5_445。131.5（4）？Ca1 Au Ca1 1_455。90.57(14) ?Sn-Au-Ca1 6_455 5_444 61.51（5）？Sn-Au-Ca1 6 5_444 61.51（5）？锡-金-钙1 1_556 5_444 166.45（12）？Ca2 Au Ca1。5_444 69.0(2) ?Au-Au Ca1 2 5_444 62.31（10）？Ca2 Au Ca1 5_545 5_444 102.76（15）？Ca2 Au Ca1 5_445 5_444 102.76（15）？Ca1 Au Ca1 1_455 5_444 124.3（2）？Ca1 Au Ca1。5_444 124.3(2) ?金锡金6_554 6_454 118.87（9）？金锡金6_554 1_554 118.23（5）？金锡金6_454 1_554 118.23（5）？金锡锡6_554 2_565 93.75（6）？金锡锡6_454 2_565 93.75（6）？金锡锡1_554 2_565 104.13（6）？Au-Sn-Ca1 6_554 1_454 156.94（10）？Au-Sn-Ca1 6_454 1_454 70.37（16）？Au-Sn-Ca1 1_554 1_454 66.55（19）？锡锡Ca1 2_565 1_454 63.74（7）？Au-Sn-Ca1 6_554 1_554 70.37（16）？Au-Sn-Ca1 6_454 1_554 156.94（10）？金锡Ca1 1_554 1_55466.55（19）？锡锡Ca1 2_565 1_554 63.74（7）？Ca1锡Ca1 1_454 1_554 93.7（3）？Au-Sn-Ca1 6_554 5_444 65.84（7）？Au-Sn-Ca1 6_454 5_444 65.84（7）？Au-Sn-Ca1 1_554 5_444 122.06（18）？锡锡钙2_565 5_444 133.81（16）？Ca1 Sn Ca1 1_454 5_444 133.07（11）？Ca1 Sn Ca1 1_554 5_444 133.07（11）？金锡钙6_554。64.61(6) ?Au-Sn-Ca2 6_454。64.61（6）？金锡钙1_554。169.01(14) ?锡锡钙2_565。64.88(11) ?Ca1-Sn Ca21_ 454组成。106.53(16) ?Ca1锡Ca2 1_554。106.53(16) ?Ca1 Sn Ca2 5_444。68.9(2) ?金锡钙6_554 5_444 134.14（13）？Au-Sn-Ca2 6_454 5_444 61.05（16）？Au-Sn-Ca2 1_554 5_444 63.2（2）？锡锡钙2_565 5_444 131.67（7）？Ca1 Sn Ca2 1_454 5_444 68.86（12）？Ca1 Sn Ca2 1_554 5_444 129.7（4）？Ca2 Sn Ca2 _444 75.76（15）？Ca2 Sn Ca2。5_444 123.4(3) ?金锡钙6_554 5_544 61.05（16）？金锡钙6_454 5_544 134.14（13）？Au-Sn Ca21_554 5_544 63.2（2）？锡锡钙2_565 5_544 131.67（7）？Ca1 Sn Ca2 1_454 5_544 129.7（4）？Ca1 Sn Ca2 1_554 5_544 68.86（12）？Ca2 Sn Ca2 _444 5_544 75.76（15）？Ca2 Sn Ca2。5_544 123.4(3) ?Ca2 Sn Ca2 _444 5_544 86.54（14）？锡-钙-锡2_666 1_656 52.52（15）？锡-钙-锡2_666 1_556 117.1（4）？锡Ca1锡1_656 1_556 93.7（3）？锡-钙-锡2_666 2_566 93.7（3）？锡-钙-锡1_656 2_566 117.1（4）？锡-钙-锡1_556 2_566 52.52（15）？锡-钙-锡2_666 6 133.07（11）？锡-钙-锡1_656 6 94.03（5）？锡-钙-锡1_556 6 94.03（5）？锡-钙-锡2_566 6 133.07（11）？锡-钙-锡2_666 5 94.03（5）？锡-钙-锡1_656 5 133.07（11）？锡-钙-锡1_556 5 133.07（11）？锡-钙-锡2_566 5 94.03（5）？锡钙锡6 5 87.6（3）？锡钙金2_666。163.2(3) ?Sn-Ca1-Au 1_656。113.27(9) ?锡钙金1_556。50.09(5) ?锡钙金2_566。85.44(6) ?锡钙金6。48.85(10) ?锡钙金5。102.8(3) ?锡钙金2_666 2_665 50.09（5）？锡钙金1_656 2_665 85.44（6）？锡钙金1_556 2_665 163.2（3）？锡-钙-金2_566 2_665 113.27（9）？锡钙金6 2_665 102.8（3）？锡钙金5 2_665 48.85（10）？Au-Ca1-Au。2_665 144.8(4) ?锡钙金2_666 2_565 113.27（9）？锡钙金1_656 2_565 163.2（3）？锡钙金1_556 2_565 85.44（6）？锡钙金2_566 2_565 50.09（5）？锡钙金6 2_565 102.8（3）？锡钙金5 2_565 48.85（10）？Au-Ca1-Au。2_565 78.87(11) ?Au-Ca1 Au 2_665 2_565 90.57（13）？锡钙金2_666 1_655 85.44（6）？锡钙金1_656 1_655 50.09（5）？锡-钙-金1_556 1_655 113.27（9）？锡钙金2_566 1_655 163.2（3）？锡钙金6 1_655 48.85（10）？锡钙金5 1_655 102.8（3）？Au-Ca1-Au。1_6 55 90.57（13）？Au-Ca1 Au 2_665 1_655 78.87（11）？Au-Ca1 Au 2_565 1_655 144.8（4）？锡钙金2_666 5 48.12（15）？锡钙金1_656 5 75.1（2）？锡钙金1_556 5 75.1（2）？锡钙金2_566 5 48.12（15）？锡钙金6 5 163.9（3）？锡钙金5 5 108.51（7）？Au-Ca1-Au。5 124.3(2) ?Au-Ca1 Au 2_665 5 88.43（13）？Au-Ca1 Au 2_565 5 88.43（13）？Au-Ca1 Au 1_655 5 124.3（2）？锡钙金2_666 6 75.1（2）？Sn-Ca1-Au 1_656 6 48.12（15）？锡钙金1_556 6 48.12（15）？锡-钙-金2_566 6 75.1（2）？锡钙金6 6 108.51（7）？锡钙金5 6 163.9（3）？Au-Ca1-Au。6 88.43(13) ?Au-Ca1 Au 2_665 6 124.3（2）？Au-Ca1 Au 2_565 6 124.3（2）？Au-Ca1 Au 1_655 6 88.43（13）？Au-Ca1 Au 5 6 55.4（2）？金-钙-金2_565。82.5(3) ?Au-Ca2-Au2_565 6_454 134.46（13）？Au-Ca2-Au。6_454 93.35(6) ?金-钙-金2_565 5_554 93.35（6）？Au-Ca2-Au。5_5 54 134.46（13）？Au-Ca2-Au 6_454 5_554 119.4（4）？Au-Ca2-Au2_565 5_454 93.35（6）？Au-Ca2-Au。5_454 134.46(13) ?Au Ca2 Au 6_454 5_454 58.25（13）？金钙金5_554 5_454 91.0（2）？金-钙-金2_565 6_554 134.46（13）？Au-Ca2-Au。6_554 93.35(6) ?金钙金6_454 6_554 91.0（2）？金钙金5_554 6_554 58.25（13）？Au-Ca2-Au 5_454 6_554 119.4（4）？金-钙-锡2_565。163.9(3) ?Au-Ca2-Sn。113.61(8) ?Au-Ca2-Sn 6_454。48.42(14) ?金钙锡5_554。75.5(2) ?Au-Ca2-Sn 5_454。75.5（2）？金-钙-锡6_554。48.42(14) ?金-钙-锡2_565 2_565113.61（8）？金-钙-锡。2_565 163.9(3) ?金钙锡6_454 2_565 75.5（2）？金钙锡5_554 2_565 48.42（14）？金钙锡5_454 2_565 48.42（14）？金钙锡6_554 2_565 75.5（2）？锡-钙-锡。2_565 50.2(2) ?Au-Ca2-Sn 2_565 5 48.58（11）？金-钙-锡。5 102.4(3) ?Au-Ca2-Sn 6_454 5 164.2（3）？Au Ca2 Sn 5_554 5 48.51（4）？Au-Ca2-Sn 5_454 5 108.36（8）？金钙锡6_554 5 89.12（6）？锡-钙-锡。5 123.4(3) ?锡钙锡2_565 5 89.22（13）？Au-Ca2-Sn 2_565 6_455 102.4（3）？金-钙-锡。6_455 48.58(11) ?Au-Ca2-Sn 6_454 6_455 48.51（4）？金钙锡5_554 6_455 164.2（3）？金钙锡5_454 6_455 89.12（6）？Au-Ca2-Sn 6_554 6_455 108.36（8）？锡-钙-锡。6_455 89.22(13) ?锡钙锡2_565 6_455 123.4（3）？锡钙锡5 6_455 145.5（4）？Au-Ca2-Sn 2_565 6 102.4（3）？金-钙-锡。6 48.58(11) ?Au-Ca2-Sn 6_454 6 108.36（8）？金钙锡5_554 6 89.12（6）？Au Ca2 Sn 5_454 6 164.2（3）？金钙锡6_554 6 48.51（4）？锡-钙-锡。6 89.22(13) ?锡-钙-锡2_565 6 123.4（3）？锡钙锡5 6 83.34（14）？锡钙锡6_455 6 86.55（14）？金钙锡2_565 5_455 48.58（11）？金-钙-锡。5_455 102.4(3) ?Au-Ca2-Sn 6_454 5_455 89.12（6）？Au-Ca2-Sn 5_554 5_455 108.36（7）？Au-Ca2-Sn 5_454 5_455 48.51（4）？金-钙-锡6_554 5_455 164.2（3）？锡-钙-锡。5_455 123.4(3) ?锡钙锡2_565 5_455 89.22（13）？锡钙锡5 5_455 86.55（14）？锡钙锡6_455 5_455 83.34（14）？锡-钙-锡6 5_455 145.5（4）？_shelx _ hkl文件；2 0 0 9786.07 243.32-2 0 9005.54 355.294 0 0 5706.45 159.27-4 0 0 5801.80 236.85-1 0 -1 2763.34 83.611 0 -1 2687.82 83.111 0 1 2831.71 71.721 0 -1 2639.19 73.01-1 0 -1 2680.45 108.56-1 0 1 2840.75 106.64-3 0 -1 1538.15 77.00-3 0 1 1680.06 75.363 0 -1 1564.24 50.503 0 1 1663.76 48.86-5 0 1 703.49 49.755 0 -1 663.98 33.93-5 0 -1 689.47 53.690 0 -2 2760.67 82.860 0 2 2611.20 109.280 0 -2 2725.88 70.440 0 2 2643.98 67.63-2 0 -2 2135.75 67.402 0 -2 2090.89 64.202 0 -2 2077.61 60.25-2 0 2 1988.01 85.832 0 2 2079.01 56.43-2 0 -2 2074.69 92.66-4 0 -2 1047.96 64.24-4 0 2 981.24 56.214 0 -2 1058.31 40.71-1 0 -3 8936.32 367.671 0 -3 9631.92 245.71-1 0 -3 9993.67 284.67-1 0 3 9538.09 356.6810-3 9306.83 282.993 0 -3 6332.16 171.64-3 0 3 6373.43 245.11-3 0 -3 5893.98 253.79-3 0 -3 6403.12 193.695 0-3 3142.96 104.27-5 0 -3 3150.26 157.620 0 4 2686.86 115.030 0 -4 2626.73 70.860 0 -4 2594.70 85.392 0 -4 1983.60 64.44-2 0 -4 1902.33 67.10-2 0 4 2007.04 83.372 0 -4 1877.42 59.334 0 -4 957.34 41.19-4 0 -4 926.56 65.70-1 0 5 1800.36 82.75-1 0 -5 1742.98 92.96-1 0 -5 1731.85 64.951 0 -5 1883.34 54.731 0 -5 1958.82 64.23-3 0 -5 1202.49 49.16-3 0-5 1250.12 78.493 0 -5 1185.48 45.430 0 6 5248.25 217.040 0 -6 5381.95 168.842 0 -6 3995.67 135.71-2 0 -6 4362.44 139.16-2 0 -6 4117.33 196.212 0 -6 4383.82 120.514 0 -6 2405.50 84.87-4 0 -6 2472.17 138.021 0 -7 1650.76 64.981 0 7 1848.63 57.311 0 7 1856.17 92.491 0-7 1682.78 54.34-1 0 -7 1606.36 66.753 0 -7 1003.14 42.52-3 0-7 1063.58 81.54-3 0 -7 973.54 46.180 0 -8 1185.63 53.472 0 8 823.37 39.512 0 -8 878.24 36.21-2 0-8 902.21 43.412 0 8 811.76 63.501 0 -9 2098.80 82.38-1 0 -9 2002.83 82.343 0 -9 1483.68 60.080 0 -10 953.47 50.401 -1 0 15.14 3.07-1 1 0 14.89 5.16-1 -1 0 11.56 5.25-1 1 0 11.38 2.353 -1 0 4.18 3.23-3 1 0 7.66 6.40-3 -1 0 2.74 5.143 1 0 9.01 3.60-5 1 0 4.66 7.91-5 -1 0 1.05 7.810 1 -1 554.22 22.580 1-1 530.34 20.450 -1 -1 526.91 19.320 1 1 538.27 29.562 -1 1 343.18 14.652 1 1 351.75 13.782 1 -1 381.35 16.33-2 1 1 366.79 24.18-2 1 -1 387.43 14.822 -1 -1 386.31 15.742 1 -1 382.84 19.48-2 1 -1 377.54 24.85-2 -1 -1 392.70 25.96-2 -1 1 359.42 21.89-4 -1 1 181.80 20.704 -1 1 182.88 13.79-4 -1 -1 183.09 22.59-4 1 179.95 21.34-4 1 -1 168.65 22.054 1 -1 175.97 14.254 -1 -1 190.22 14.501 -1 -2 1060.67 31.85-1-1-2 958.07 55.37-1 1 2 1079.55 49.331 1 -2 1047.36 37.42-1 1 -2 1035.44 48.07-1 -1 2 1118.25 42.09-1 -1 -2 1016.38 36.77-1 1 -2 1039.88 36.101 -1 -2 1055.15 34.543 -1 -2 517.47 23.353 1 -2 544.86 24.61-3 -1 -2 534.71 38.53-3 -1 2 561.16 32.00-3 1 -2 544.47 37.98-3 1 2 545.18 34.39-3 1 -2 516.37 22.273 -1 2 559.18 21.87-5 1 2 222.60 26.28-5-1-2 235.01 30.785 1 -2 221.63 19.705 -1 -2 221.90 19.76-5 1 -2 261.92 32.870 -1 -3 144.08 7.110 1 3 126.46 17.900 1 -3 134.19 9.700 -1 -3 130.81 8.840 1 -3 158.32 14.94-2 -1 -3 77.89 16.24-2 1 -3 73.90 12.502 1 -3 70.53 7.81-2 -1 3 48.85 7.12-2 -1 -3 66.36 7.83-2 1 3 51.35 10.63-2 1 -3 77.87 7.362-1-3 80.87 5.792 -1 -3 65.58 6.722 1 -3 75.33 7.344 -1 -3 40.62 8.98-4 -1 -3 44.61 15.744 1-3 41.41 9.23-4 1 -3 40.04 14.79-4 1 3 23.24 9.531 1 -4 101.01 9.09-1 -1 4 106.13 9.011 -1 -4 101.33 7.481 1 -4 94.11 8.031 -1 -4 105.77 8.23-1 1 4 86.90 14.71-1 1 -4 96.30 15.43-1 1 -4 91.55 8.86-1 -1 -4 91.90 8.81-3 1 -4 60.70 15.88-3 -1 -4 70.89 9.183 -1 -4 61.77 8.89-3 1 -4 61.73 8.62-3 -1 -4 103.39 21.773 1-4 68.36 10.27-3 1 4 70.21 12.705 -1 -4 32.43 10.095 1 -4 26.54 10.60-5 -1 -4 54.70 21.02-5 1 -4 38.58 17.550 -1 -5 931.51 29.360 -1 -5 919.35 37.030 1 -5 889.89 29.730 1 5 934.43 58.030 1 -5 952.52 38.610 -1 5 956.35 48.672 1 -5 699.00 31.13-2 1 -5 720.72 52.212 -1 -5 682.07 27.77-2 1 5 733.79 43.422-1-5 695.20 29.42-2 -1 -5 732.30 57.29-2 -1 -5 715.74 32.612 1 -5 691.13 29.46-4 -1 -5 339.03 40.054 1-5 341.57 24.534 -1 -5 345.27 23.57-4 1 -5 385.09 41.841 1 6 68.32 11.57-1 -1 -6 94.22 10.511 1 -6 79.42 8.49-1 1 -6 79.24 10.321 -1 -6 101.76 10.55-1 1 6 65.39 16.441 1 -6 95.49 11.081 -1 -6 86.45 8.44-1 1 -6 113.88 18.911 1 6 67.86 18.653 -1 -6 45.40 9.433 1 -6 49.99 10.17-3 -1 -6 65.35 22.89-3 1 -6 63.61 10.29-3-1-6 55.80 10.49-3 1 -6 74.49 22.860 -1 -7 42.64 8.690 1 7 42.64 14.490 1 -7 48.71 9.592 1 -7 30.17 8.292 1 -7 35.05 7.942 -1 -7 48.20 8.57-2 1 -7 27.73 16.182 1 7 36.46 15.94-2 1 -7 30.70 8.61-2 -1 -7 27.12 8.07-4 -1 -7 17.51 16.544 -1 -7 16.07 8.594 1 -7 35.76 11.79-4 1 -7 34.00 19.71-1 1-8 397.65 26.98-1 -1 -8 363.55 25.001 1 -8 381.27 25.721 -1 -8 384.53 24.891 1 8 398.57 39.023 1-8 298.63 22.573 1 8 274.04 22.403 1 8 295.94 37.18-3 1 -8 263.31 21.97-3 -1 -8 238.61 21.873 -1 -8 260.48 20.800 1 -9 19.28 8.820 -1 -9 15.00 7.37-2 -1 -9 15.79 7.73-2 1 -9 26.76 9.761 -1 -10 36.22 11.761 1 -10 21.80 10.910 2 0 4940.73 191.06-2 2 0 4278.77 127.29-2 2 0 4103.46 169.38-2 -2 0 4343.97 171.952 -2 0 4148.46 115.69-4-2 0 2299.09 109.594 2 0 2292.60 73.294 -2 0 2315.67 74.54-4 2 0 2304.10 111.00-1 2 1 4027.43 154.071 2 -1 3713.20 124.74-1 2 -1 3911.91 119.63-1 2 -1 3743.71 150.82-3 2 1 2596.27 108.223 2 -1 2285.86 73.66-3 -2 -1 2064.63 108.85-3 2 -1 2366.72 109.15-3 -2 1 2622.58 105.023 2 -1 2236.59 84.693 2 1 2559.79 70.533 -2 -1 2351.25 72.335 2-1 1007.42 46.02-5 -2 -1 1122.74 73.445 -2 -1 1104.46 48.44-5 2 1 1118.05 68.86-5 2 -1 1103.89 71.920 2 2 3802.02 161.060 2 -2 3741.39 120.950 2 -2 3909.52 145.232 2 -2 3098.37 103.90-2 2 -2 3132.05 96.082 -2 -2 3069.17 86.68-2 2 2 2843.62 128.75-2 -2 -2 3178.59 138.88-2 2 -2 3082.42 128.09-2 -2 2 2902.74 120.324 -2 -2 1548.37 55.354 2 -2 1643.08 58.54-4 2 2 1377.40 78.96-4 2 -2 1575.77 85.27-4 -2 -2 1618.05 87.801 -2 -3 4365.36 118.731 2 -3 4249.86 139.291-2-3 4500.08 134.591 2 3 4171.31 186.941 2 3 4199.16 115.64-1 2 -3 4583.46 137.67-1 2 3 4287.87 181.38-1 -2 -3 4394.73 136.32-1 2 -3 4408.28 173.01-3 2 3 2891.67 128.863 -2 -3 2967.39 88.753 2 -3 3020.83 92.57-3 2 -3 2939.96 133.67-3 -2 -3 2950.09 140.24-3 2 -3 2891.65 95.505-2-3 1445.41 58.395 2 -3 1419.04 60.79-5 2 3 1361.40 80.57-5 2-3 1406.69 89.92-5 -2 -3 1471.88 92.300 2 -4 2903.76 117.520 2 4 3073.12 136.360 2 -4 2772.01 96.400-2-4 2780.20 93.79-2 2 4 2317.17 102.742 2 -4 2049.64 75.97-2 2 -4 2128.90 101.972 2 -4 2217.45 69.87-2 2 -4 2115.01 74.11-2 -2 -4 2102.54 113.76-2 -2 -4 2152.42 74.862 -2 -4 2148.50 66.00-4 2 -4 1091.10 74.00-4 -2 -4 1117.77 76.83-4 2 4 1223.03 66.534 2 -4 1184.11 51.094 -2 -4 1128.69 47.241 -2 -5 1833.16 55.531 -2 -5 1823.37 63.51-1 -2 -5 1875.12 66.101 2-5 1854.23 59.031 2 5 1738.11 61.37-1 2 -5 1890.64 67.17-1 2 -5 1770.80 87.231 2 5 1608.17 97.601 2 -5 1787.48 66.783 2 -5 1224.05 49.573 -2 -5 1199.03 45.70-3 -2 -5 1147.03 80.48-3 2 -5 1240.70 74.71-3 2 -5 1170.44 48.18-3 2 5 1127.59 66.60-3 -2 -5 1242.00 50.010 2 -6 3554.28 117.680 -2 -6 3420.37 114.010 2 6 3282.38 158.92-2 2 6 2826.56 133.712 2 -6 2911.07 90.54-2 2 -6 2784.94 99.972 -2 -6 2905.19 87.372 2 -6 2873.88 100.57-2 2-6 2919.06 140.77-2 -2 -6 2877.06 100.222 2 6 2763.94 140.772 2 6 2914.21 87.91-4 2 -6 1736.95 109.13-4 -2 -6 1723.57 110.674 2 -6 1785.27 71.154 -2 -6 1626.39 65.40-1 -2 -7 1067.74 47.971 2 -7 1129.59 50.32-1 2 7 1183.01 71.041 2 -7 1083.32 41.171 2 7 1205.07 76.91-1 2 -7 1121.25 50.131 -2 -7 1088.96 46.993 2 -7 799.92 39.983 -2 -7 761.04 36.64-3-2-7 731.69 38.893 2 7 771.78 59.093 2 7 781.94 36.75-3 2 -7 769.57 40.360 -2 -8 634.00 33.630 2 -8 618.41 35.350 2 8 541.65 46.702 2 -8 528.54 28.66-2 2 -8 539.39 32.842 2 8 503.56 31.10-2 -2 -8 527.92 31.592 2 -8 506.19 31.422 2 8 452.54 48.58-1 -2 -9 1871.23 78.191 2 -9 1842.71 79.171 -2 -9 1947.39 77.51-1 2-9 1960.35 81.56-1 3 0 109.24 13.211 3 0 104.22 14.52-1 3 0 111.62 10.63-3 -3 0 86.14 16.12-3 3 0 56.45 13.35-5 3 0 35.35 14.370 3 -1 3672.79 120.760 3 1 3634.06 152.120 3 -1 3558.10 142.202 3 -1 2818.92 99.27-2 3 -1 2877.38 120.25-2 3 -1 2961.80 90.80-2 -3 -1 2891.12 128.43-2 -3 1 2793.49 119.60-2 3 1 2740.41 122.27-2 3 1 2603.17 90.49-4 3 -1 1507.95 83.164 3 -1 1489.39 56.994 -3 -1 1522.72 56.18-4 -3 -1 1573.56 85.54-4 3 1 1504.96 82.321 3-2 2437.37 87.03-1 3 2 2371.78 109.011 3 2 2475.38 70.83-1 3 -2 2267.44 98.96-1 3 -2 2339.32 80.871 3 2 2469.13 114.36-3 -3 -2 1533.36 85.93-3 3 -2 1552.18 79.043 3 -2 1358.69 63.053 -3 -2 1494.40 52.74-3 3 2 1631.53 79.61-5 -3 -2 747.53 59.365 -3 -2 713.81 38.40-5 3 -2 729.47 57.90-5 3 2 754.12 55.205 3 -2 646.95 38.130 3-3 171.73 11.900 3 -3 159.18 14.062 3 -3 113.97 14.09-2 3 -3 104.76 14.96-2 3 -3 109.52 10.942-3-3 100.76 10.60-2 3 3 171.15 21.074 3 -3 39.04 10.74-4 -3 -3 49.48 17.92-4 3 -3 56.72 17.574 -3 -3 48.46 10.13-4 3 3 90.05 18.281 3 -4 2915.37 100.17-1 3 -4 2647.38 96.921 3 4 2874.91 139.96-1 3 -4 3082.32 121.40-1 3 4 2634.12 134.72-3 3 4 2082.81 103.99-3 3 -4 2028.01 103.49-3 3 -4 1889.36 71.083 -3 -4 2059.31 68.523 3 -4 2070.22 73.90-3-3-4 2094.32 113.91-5 3 4 984.44 67.580 -3 -5 1259.99 50.030 3 -5 1338.88 55.510 3 5 1393.35 83.132 3 -5 1130.62 46.872 3 -5 1092.51 50.07-2 3 -5 1136.17 66.87-2 3 5 1174.16 71.352 -3 -5 1090.98 41.77-2 3 -5 1082.11 47.122 3 5 1138.64 71.082 3 5 1125.60 44.09-4 -3 -5 587.88 56.23-4 3 -5 609.85 54.254 3 -5 600.34 37.81-4 3 5 679.47 50.964 -3 -5 598.69 33.60-1 -3 -6 110.19 11.981 3 6 203.21 31.751 3 -6 131.93 15.391-3-6 126.50 11.45-1 3 -6 114.27 13.451 -3 -6 127.40 12.22-3 3 6 172.90 28.49-3 3 -6 80.72 12.273 3 6 139.49 24.753 3 -6 102.60 16.333 -3 -6 83.47 12.85-3 3 -6 88.21 23.390 -3 -7 1801.74 67.510 3 7 1679.12 102.100 3 -7 1786.41 72.852 3 7 1458.68 93.592 -3 -7 1571.23 55.502 3 7 1458.18 58.02-2 3 -7 1549.03 64.18-2 -3 -7 1498.93 61.902 3-7 1520.92 58.72-2 3 7 1389.89 88.932 3 -7 1525.92 65.63-1 3 -8 684.31 39.041 3 -8 650.65 39.171 3 8 706.83 61.53-1 3 8 644.76 55.101 -3 -8 672.02 35.12-1 -3 -8 597.28 34.473 -3 -8 501.92 30.533 3 -8 485.05 33.70-3 3 -8 478.43 33.200 -3 -9 63.59 12.400 3 -9 50.70 12.942 3 9 88.81 28.120 4 0 2781.01 102.910 4 0 3124.62 128.64-2 4 0 2355.49 108.242 4 0 2404.85 104.912 4 0 2336.82 64.69-2 4 0 2367.56 81.27-4 4 0 1233.62 73.30-1 4 1 930.78 58.221 4 -1 1094.27 49.041 4 -1 1126.22 54.64-1 4 -1 1157.71 55.61-1 4 -1 1185.46 46.601 4 1 957.30 60.31-3 4 1 597.68 45.13-3 -4 -1 731.94 50.773 4 -1 737.61 37.52-3 4 -1 732.25 46.86-5 4 -1 383.79 38.96-5 4 1 274.10 34.130 4 2 1287.61 70.190 4 -2 1117.90 53.110 4 -2 1092.07 49.71-2 4 -2 808.76 36.41-2 4-2 822.10 48.512 4 -2 793.31 44.45-2 4 2 854.38 55.832 4 2 1005.87 55.832 4 2 910.86 33.70-4 -4 -2 470.50 44.324 4 -2 483.97 31.63-4 4 2 475.46 40.67-4 4 -2 420.16 38.98-1 4 3 2091.82 109.46-1 4 -3 2092.80 92.41-1 4 -3 1999.77 76.761 4 -3 2242.12 83.451 4 3 2146.50 111.57-3 4 -3 1327.97 73.793 4 3 1322.12 46.11-3 4 3 1378.95 79.243 4 -3 1269.24 61.673 4 3 1323.41 74.54-5 -4 -3 736.98 63.595 4 -3 805.76 47.700 4-4 960.26 45.070 4 4 986.22 69.26-2 4 -4 704.23 45.932 4 4 707.51 32.91-2 4 -4 749.89 35.26-2 4 4 677.99 54.542 4 -4 763.03 41.442 4 4 698.44 53.174 -4 -4 415.02 27.31-4 4 -4 431.46 42.30-4 4 4 393.14 40.854 4 -4 434.41 31.251 4 -5 812.66 44.06-1 4 -5 862.42 42.291 4 5 910.93 69.69-1 4 5 863.43 66.813 4 -5 503.28 32.17-3 4-5 508.90 45.623 4 5 547.98 45.113 -4 -5 516.85 29.15-3 4 5 605.84 53.973 4 5 524.24 27.810 4 6 1075.26 77.950 4 -6 952.70 48.46-2 4 -6 812.81 41.542 4 6 814.19 63.02-2 4 6 795.23 65.702 4 -6 833.24 46.25-4 4 6 520.62 51.51-1 4 7 632.14 59.49-1 4 -7 649.32 38.491 4 7 681.98 63.181 4 -7 668.72 40.443 4-7 414.54 31.403 4 7 459.06 45.293 -4 -7 425.56 28.323 4 7 444.59 27.59-3 4 -7 437.81 29.91-3 4 7 490.88 51.770 4 8 514.41 53.740 4 -8 528.03 35.76-2 4 -8 433.38 31.382 4 -8 415.56 33.532 4 8 418.32 48.72-2 4 8 393.44 46.352 4 -8 453.70 30.111 4 9 286.65 42.451 5 0 521.03 30.27-1 5 0 474.95 36.141 5 0 469.73 35.97-1 5 0 467.65 30.14-3 5 0 357.34 33.153 5 0 329.22 23.790 5 1 3659.68 163.480 5 -1 3709.51 153.320 5-1 3556.99 129.54-2 5 -1 3054.34 103.34-2 5 -1 2950.06 132.572 5 1 3004.70 134.25-2 5 1 2797.19 138.872 5 -1 3101.20 109.70-4 5 -1 1702.61 92.11-4 5 1 1549.97 90.93-1 5 -2 3974.04 164.76-1 5 2 4114.05 181.921 5 -2 3873.64 142.561 5 2 4092.51 181.29-1 5 -2 3974.21 136.08-3 5 -2 2616.35 127.933 5 2 2743.73 127.283 5 2 2805.43 79.323 5-2 2874.87 107.40-3 5 2 2792.43 137.280 5 3 502.87 48.420 5 -3 505.54 31.63-2 5 3 299.81 37.01-2 5-3 458.99 26.002 5 -3 428.37 32.412 5 3 326.43 35.00-2 5 -3 409.24 32.034 5 3 203.89 17.88-4 5 3 197.66 30.074 5 3 199.86 27.79-4 5 -3 245.39 30.814 5 -3 334.33 28.79-1 5 4 2093.30 118.011 5 4 1788.06 111.451 5 -4 2091.48 84.15-1 5 -4 2078.23 79.503 5 4 1436.28 51.503 5 -4 1349.01 67.933 5 4 1397.02 82.81-3 5 -4 1475.50 82.10-3 5 4 1479.45 95.520 5 5 3817.75 185.220 5 -5 3491.33 130.83-2 5 -5 2787.27 105.15-2 5 5 2854.57 154.112 5 -5 2917.99 115.912 5 5 3033.34 147.301 5 -6 318.51 27.94-1 5 -6 298.27 24.191 5 6 204.98 38.64-1 5 6 205.98 39.603 5 6 147.27 27.37-3 5 6 162.59 37.293 5-6 210.87 21.140 5 -7 1129.43 58.280 5 7 1211.73 92.282 5-7 896.01 46.072 5 -7 1063.95 59.162 5 7 979.34 76.60-2 5 -7 930.31 49.98-2 5 7 998.55 81.57-1 5 8 1808.15 117.96-1 5 -8 1704.36 79.161 5 8 1958.68 121.791 5 -8 1713.99 82.920 6 0 77.20 18.580 6 0 65.44 13.822 6 0 59.72 11.96-2 6 0 99.76 19.87-4 6 0 35.40 15.20-1 6 -1 675.80 46.42-1 6 1 661.11 50.98-1 6 -1 659.88 39.12-1 6 1 625.86 38.381 6 -1 670.07 39.841 6 1 636.88 48.183 6 -1 492.86 32.17-3 6 1 428.53 42.17-3 6-1 419.46 37.810 6 2 669.80 55.670 6 -2 679.89 41.05-2 6 -2 557.17 39.76-2 6 2 485.12 48.02-2 6 -2 562.04 31.842 6 -2 560.61 37.042 6 2 455.53 41.16-4 6 -2 347.21 37.88-4 6 2 307.78 38.45-1 6 3 36.61 18.991 6 3 32.74 16.531 6 -3 24.65 11.43-1 6 -3 28.49 9.823 6 3 32.31 14.32-3 6 -3 30.41 13.563 6-3 14.09 10.470 6 4 456.97 52.040 6 -4 477.06 33.06-2 6 4 328.21 43.842 6 -4 359.06 31.65-2 6-4 404.40 27.602 6 4 418.88 42.13-1 6 5 493.16 55.35-1 6 -5 436.85 31.331 6 -5 427.15 35.071 6 5 365.36 45.263 6 -5 249.42 28.97-3 6 5 309.63 46.423 6 5 253.03 31.720 6 6 1.49 18.680 6 -6 0.52 7.46-2 6 6 23.51 20.882 6 -6 28.58 14.27-2 6 -6 13.64 9.072 6 6 5.32 12.47-1 6 7 225.83 46.16-1 6 -7 281.64 26.741 6-7 256.06 28.781 6 7 203.60 42.491 7 0 1089.62 53.11-1 7 0 1023.23 68.79-1 7 0 1027.93 56.16-3 7 0 751.28 57.663 7 0 689.32 40.400 7 -1 2451.76 100.630 7 1 2412.93 125.422 7 -1 2228.39 91.64-2 7 -1 2253.46 113.20-2 7 1 2196.55 122.894 7 1 1449.58 70.00-1 7 2 2087.27 116.261 7 2 1799.33 104.291 7 -2 1847.67 84.57-1 7-2 1963.08 83.013 7 -2 1417.89 67.06-3 7 2 1337.78 93.44-3 7 -2 1431.95 83.650 7 3 1162.04 82.940 7-3 973.93 55.372 7 3 929.80 62.94-2 7 3 897.07 73.792 7 -3 795.06 49.54-2 7 -3 829.42 45.53-1 7 -4 2441.03 96.191 7 -4 2342.33 99.561 7 4 2091.81 125.46-1 7 4 2275.86 138.003 7 -4 1624.69 78.013 7 4 1675.60 96.430 7 5 1331.13 100.490 7 -5 1304.08 66.822 7 -5 1046.24 62.01-2 7 -5 1063.77 54.962 7 5 1048.85 75.76-2 7 5 1074.89 91.881 7-6 633.59 46.69-1 7 -6 604.94 41.350 8 0 199.95 24.212 8 0 156.59 19.15-2 8 0 172.69 31.111 8 -1 392.44 32.021 8 1 373.75 29.45-1 8 -1 383.90 33.52-1 8 1 365.40 33.30-1 8 1 373.34 43.62-3 8 -1 306.04 37.450 8 2 388.05 45.290 8 -2 377.49 33.470 8 2 368.90 29.872 8 -2 310.10 28.99-2 8 2 319.10 44.601 8 3 210.83 34.571 8 -3 185.72 24.15-1 8 3 222.34 41.34-1 8 -3 201.19 23.860 8 4 236.53 43.380 8-4 256.84 27.742 8 4 201.90 32.03-1 9 0 1169.50 67.190 9 -1 875.71 55.500 9 1 951.81 54.82-1 9 2 1014.38 81.78-1 9 -2 1058.65 61.400 9 3 910.16 76.360 0 0 0.00 0.00；_shelx _hkl校验和46215_shelx文件；TITL Imm2（单位：Imm2）手机0.71073 4.5261 7.1356 7.8147 90.000 90.000 90000零4.00 0.0007 0.0011 0.0011 0.000 0.000 0.000.000LATT-2型对称-X、-Y、Z对称X、-Y、ZSYMM-X、Y、ZSFAC CA SN AU公司第4 4 4单元温度0L.S.4号机组债券飞行管理计划2平面图20ACTA公司双胞胎-1 0 0 0-1 0 0-1WGHT 0.036000 7.630500外景0.007223巴斯夫0.31256自由值0.28033澳大利亚3 0.000000 0.216501 0.682590 10.50000 0.01110 0.00738=0.01331 0.00070 0.00000 0.00000序号2 0.000000 0.307611 0.013002 10.50000 0.01454 0.01906=0.01533 0.00041 0.00000 0.00000CA1 1 0.500000 0.500000 0.805843 10.25000 0.00962 0.00598=0.00924 0.00000 0.00000 0.00000CA2 1 0.000000 0.500000 0.387602 10.25000 0.01415 0.00711=0.01151 0.00000 0.00000 0.00000HKLF 4号机组快速眼动免疫2在免疫2中REM R1=0.0276（对于326 Fo>4sig（Fo））和0.0280（对于所有330数据）使用1个约束优化REM 23参数结束工作热处理0.0360 7.6378REM最高差值峰值2.675，最深孔-1.851，1σ水平0.511Q1 1 0.0000 0.1677 0.0175 10.50000 0.05 2.68问题2 1 0.0000 0.0475 0.6839 10.50000 0.05 2.58问题3 1 0.0000 0.3862 0.6833 10.50000 0.05 2.51问题4 1 0.0000 0.4620 0.0175 10.50000 0.05 2.11问题5 1 0.5000 0.5000 0.8557 10.25000 0.05 1.41问题6 1 0.0000 0.5000 0.7604 10.25000 0.05 1.29问题7 1 0.0000 0.0601 0.0134 10.50000 0.05 1.12问题8 1 0.0000 0.5000 0.6830 10.25000 0.05 1.06问题9 1 0.1916 0.2685 0.6859 11.00000 0.05 1.02问题10 1 0.2089 0.5000 0.6806 10.50000 0.05 0.87问题11 1 0.5000 0.6908 0.7589 10.50000 0.05 0.87问题12 1 0.1184 0.1555 0.7512 11.00000 0.05 0.72问题13 1 0.5000 0.6391 0.7228 10.50000 0.05 0.72问题14 1-0.4574 0.5000 0.4063 10.50000 0.05 0.71问题15 1 0.0000 0.2143 0.4721 10.50000 0.05 0.70问题16 1 0.0000 0.1445 0.5799 10.50000 0.05 0.69问题17 1 0.0000 0.4285-0.0756 10.50000 0.05 0.68Q18 1 0.0000 0.2875 0.2197 10.50000 0.05 0.65问题19 1 0.1122 0.3333 0.1861 11.00000 0.05 0.64问题20 1 0.1731 0.2377-0.0395 11.00000 0.05 0.63；_搁置_校验和60153_shelxl版本号2013数据_全局_日志日期电子2014-06-17_日记_日期_接受日期2014-07-10_journal_name_full“结晶学报，C部分”_2014年日记_日志_卷70_期刊_第8期_日志页面_第一个773_日志_页面_最后775_日志_纸张_类别FA_日志_paper_doi 10.1107/S205322961401612X_日记_编辑_代码FN3175_publ_contact_author_name“林启生”_公共联系人作者地址；Ames实验室美国能源部353斯佩迪格大厅爱荷华州立大学艾姆斯IA 50011公司美国；_发布_联系人_作者_邮件qslin@ameslab.gov_publ_contact_author_fax？_publ_contact_author_phone电话'515-294-3513'_公共_部分_标题；钙金锡的低温形态；回路__publ_author_name（发布_作者名称）_公共_作者_地址“林奇生”；Ames实验室美国能源部爱荷华州立大学艾姆斯IA 50011公司美国；“科贝特，约翰·D。”；Ames实验室美国能源部爱荷华州立大学艾姆斯IA 50011公司美国；_公共_部分_摘要；CaAuSn的低温形式具有EuAuGe型结构（空间群伊姆2） ，使用一=4.5261（7）\%A，b条=7.1356（11）\%A和c（c）=7.8147（11）\%A。此结构是两个父结构之一其高温多晶型(卡873 K），这是一个共生体EuAuGe和SrMgSi型结构的比例为2:3。；_单元格特殊详细信息？_衍射辐射单色仪？_衍射标准编号？_精化_数量_约束0_细化_ls_abs_structure_Rogers？