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Permanganate

chemical
Permanganate, ion MnO four - Valence - 1, strong in acid solution Oxidizability The alkaline solution also has a certain degree of oxidation, and it is purple red in the solution. The common ones are potassium permanganate (KMnO₄)。
Chinese name
Permanganate
Foreign name
Permanganate ion
chemical formula
MnO₄ -

content

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potassium permanganate The oxidation of can be shown in both acid and alkaline, but it is more obvious in acid.
Permanganate
For example, olefin In Carbon carbon double bond In the cold, dilute alkaline potassium permanganate aqueous solution glycol (Its two hydroxyl groups are formed on the same side of the double bond), the adjacent diol is further oxidized to ketone or acid, and the yield is generally not high; If concentrated, hot or acidic potassium permanganate is used for oxidation, the reaction conditions are relatively strong, and the carbon carbon double bond breaks, forming ketone, acid or a mixture of ketone and acid. The structure of the product depends on the hydrogen content on the double bond alkane Substitution, such as R2C=, RCH=and H2C=in the double bond are oxidized to ketone, acid and carbon dioxide
Compounds containing permanganate are collectively referred to as permanganate
MnO four - According to solution Acid-base property Different will have different Reduction product .
The acid product is Mn 2+ , alkaline is MnO four 2- , neutral is MnO two

Correlation ion equation

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MnO four - +5NO₂ - +8H + =Mn 2+ +5NO two ↑ +4H two O
2MnO four - +5H two O two +6H + ==2Mn 2+ +5O two ↑+8H two O
5Fe 2+ +MnO four - +8H + ==5Fe 3+ +Mn 2+ +4H two O